Electrolytic properties of sulfidic ceramics on the base of calcuim thiogadolinate and barium thiosamarate

A regular research of phases on the basis of Ca(Ba)Gd(Sm)₂S₄—Gd(Sm)₂S₃(BaS) using various electrochemical methods has been carried out. The area of solid solutions, electrolytic temperature interval, average ion transfer numbers and electron transfer numbers have been determined. The structures havi...

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Опубліковано в: :Functional Materials
Дата:2006
Автори: Medvedeva, O.V., Yurlov, I.S., Kalinina, L.A., Ushakova, Yu.N., Fominykh, E.G., Shirokova, G.I., Ananchenko, B.A.
Формат: Стаття
Мова:English
Опубліковано: НТК «Інститут монокристалів» НАН України 2006
Онлайн доступ:https://nasplib.isofts.kiev.ua/handle/123456789/135011
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Electrolytic properties of sulfidic ceramics on the base of calcuim thiogadolinate and barium thiosamarate / O.V. Medvedeva, I.S. Yurlov, L.A. Kalinina, Yu.N. Ushakova, E.G. Fominykh, G.I. Shirokova, B.A. Ananchenko // Functional Materials. — 2006. — Т. 13, № 3. — С. 519-525. — Бібліогр.: 9 назв. — англ.

Репозитарії

Digital Library of Periodicals of National Academy of Sciences of Ukraine
id nasplib_isofts_kiev_ua-123456789-135011
record_format dspace
spelling Medvedeva, O.V.
Yurlov, I.S.
Kalinina, L.A.
Ushakova, Yu.N.
Fominykh, E.G.
Shirokova, G.I.
Ananchenko, B.A.
2018-06-14T13:23:22Z
2018-06-14T13:23:22Z
2006
Electrolytic properties of sulfidic ceramics on the base of calcuim thiogadolinate and barium thiosamarate / O.V. Medvedeva, I.S. Yurlov, L.A. Kalinina, Yu.N. Ushakova, E.G. Fominykh, G.I. Shirokova, B.A. Ananchenko // Functional Materials. — 2006. — Т. 13, № 3. — С. 519-525. — Бібліогр.: 9 назв. — англ.
1027-5495
https://nasplib.isofts.kiev.ua/handle/123456789/135011
A regular research of phases on the basis of Ca(Ba)Gd(Sm)₂S₄—Gd(Sm)₂S₃(BaS) using various electrochemical methods has been carried out. The area of solid solutions, electrolytic temperature interval, average ion transfer numbers and electron transfer numbers have been determined. The structures having the best electrolytic properties are established. The conductivity nature of solid electrolyte on the basis of barium thiosamarate and calcium thiogadolinate has been investigated. The data obtained allow to consider phases Ca(Ba)Gd(Sm)₂S₄—Gd(Sm)₂S₃(BaS) as ionic conductors. The possible mechanism of defect formation is proposed.
en
НТК «Інститут монокристалів» НАН України
Functional Materials
Electrolytic properties of sulfidic ceramics on the base of calcuim thiogadolinate and barium thiosamarate
Електролітичні властивості сульфідної кераміки на основі тіогадолінату тальцію та тіосамарату барію
Article
published earlier
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
title Electrolytic properties of sulfidic ceramics on the base of calcuim thiogadolinate and barium thiosamarate
spellingShingle Electrolytic properties of sulfidic ceramics on the base of calcuim thiogadolinate and barium thiosamarate
Medvedeva, O.V.
Yurlov, I.S.
Kalinina, L.A.
Ushakova, Yu.N.
Fominykh, E.G.
Shirokova, G.I.
Ananchenko, B.A.
title_short Electrolytic properties of sulfidic ceramics on the base of calcuim thiogadolinate and barium thiosamarate
title_full Electrolytic properties of sulfidic ceramics on the base of calcuim thiogadolinate and barium thiosamarate
title_fullStr Electrolytic properties of sulfidic ceramics on the base of calcuim thiogadolinate and barium thiosamarate
title_full_unstemmed Electrolytic properties of sulfidic ceramics on the base of calcuim thiogadolinate and barium thiosamarate
title_sort electrolytic properties of sulfidic ceramics on the base of calcuim thiogadolinate and barium thiosamarate
author Medvedeva, O.V.
Yurlov, I.S.
Kalinina, L.A.
Ushakova, Yu.N.
Fominykh, E.G.
Shirokova, G.I.
Ananchenko, B.A.
author_facet Medvedeva, O.V.
Yurlov, I.S.
Kalinina, L.A.
Ushakova, Yu.N.
Fominykh, E.G.
Shirokova, G.I.
Ananchenko, B.A.
publishDate 2006
language English
container_title Functional Materials
publisher НТК «Інститут монокристалів» НАН України
format Article
title_alt Електролітичні властивості сульфідної кераміки на основі тіогадолінату тальцію та тіосамарату барію
description A regular research of phases on the basis of Ca(Ba)Gd(Sm)₂S₄—Gd(Sm)₂S₃(BaS) using various electrochemical methods has been carried out. The area of solid solutions, electrolytic temperature interval, average ion transfer numbers and electron transfer numbers have been determined. The structures having the best electrolytic properties are established. The conductivity nature of solid electrolyte on the basis of barium thiosamarate and calcium thiogadolinate has been investigated. The data obtained allow to consider phases Ca(Ba)Gd(Sm)₂S₄—Gd(Sm)₂S₃(BaS) as ionic conductors. The possible mechanism of defect formation is proposed.
issn 1027-5495
url https://nasplib.isofts.kiev.ua/handle/123456789/135011
citation_txt Electrolytic properties of sulfidic ceramics on the base of calcuim thiogadolinate and barium thiosamarate / O.V. Medvedeva, I.S. Yurlov, L.A. Kalinina, Yu.N. Ushakova, E.G. Fominykh, G.I. Shirokova, B.A. Ananchenko // Functional Materials. — 2006. — Т. 13, № 3. — С. 519-525. — Бібліогр.: 9 назв. — англ.
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first_indexed 2025-12-07T19:51:20Z
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