Chemical bonds deviation in NH₃, PH₃, AsH₃, and SbH₃ molecules

• Datum: 2004
• Hauptverfasser: Okhrimenko, B.A., Gaididei, G.I., Samoilenko, D.M.
• Format: Artikel
• Sprache: English
• Veröffentlicht: НТК «Інститут монокристалів» НАН України 2004
• Schriftenreihe: Functional Materials
• Online Zugang: https://nasplib.isofts.kiev.ua/handle/123456789/135253
• Назва журналу: Digital Library of Periodicals of National Academy of Sciences of Ukraine
• Zitieren: Chemical bonds deviation in NH₃, PH₃, AsH₃, and SbH₃ molecules / B.A.Okhrimenko, G.I.Gaididei, D.M.Samoilenko // Functional Materials. — 2004. — Т. 11, № 1. — С. 136-141. — Бібліогр.: 8 назв. — англ.

Force matrices for PH3, ASH3 and SbH molecules have been computed. Approximation for two anharmonic parameters separately for stretching and bending vibrations is used. Form parameters for the investigated molecules are obtained. X-H bond deviation angles are calculated to be 3.9°, 5.3°, and 5.4°, r...