Electronic structure peculiarities of disordered Mn and Co diphosphates
Electronic structure peculiarities of disordered diphosphate —Mn₂₋ₓCoₓP₂O₇*5H₂O, with x = 0, 0.6, 1.0, 1.9, 2.0, were studied by XPS and X-ray emission spectroscopy. Substitution in the different degree of cobalt by manganese leads to a charge redistribu¬tion in the metal sublattice and results in i...
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| Published in: | Functional Materials |
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| Date: | 2012 |
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| Format: | Article |
| Language: | English |
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НТК «Інститут монокристалів» НАН України
2012
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| Online Access: | https://nasplib.isofts.kiev.ua/handle/123456789/135380 |
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| Cite this: | Electronic structure peculiarities of disordered Mn and Co diphosphates / V.L. Karbivskyy, S.S. Smolyak, Yu.A. Zagorodniy, V.H. Kasiyanenko // Functional Materials. — 2012. — Т. 19, № 4. — С. 459-463. — Бібліогр.: 6 назв. — англ. |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine| _version_ | 1862621628480880640 |
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| author | Karbivskyy, V.L. Smolyak, S.S. Zagorodniy, Yu.A. Kasiyanenko, V.H. |
| author_facet | Karbivskyy, V.L. Smolyak, S.S. Zagorodniy, Yu.A. Kasiyanenko, V.H. |
| citation_txt | Electronic structure peculiarities of disordered Mn and Co diphosphates / V.L. Karbivskyy, S.S. Smolyak, Yu.A. Zagorodniy, V.H. Kasiyanenko // Functional Materials. — 2012. — Т. 19, № 4. — С. 459-463. — Бібліогр.: 6 назв. — англ. |
| collection | DSpace DC |
| container_title | Functional Materials |
| description | Electronic structure peculiarities of disordered diphosphate —Mn₂₋ₓCoₓP₂O₇*5H₂O, with x = 0, 0.6, 1.0, 1.9, 2.0, were studied by XPS and X-ray emission spectroscopy. Substitution in the different degree of cobalt by manganese leads to a charge redistribu¬tion in the metal sublattice and results in increase of the chemical bond ionicity between oxygen anions and the metal cations. Such charge redistribution is responsible for forma¬tion of the states laying in the upper part of the valence band.
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| first_indexed | 2025-12-07T13:25:15Z |
| format | Article |
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| id | nasplib_isofts_kiev_ua-123456789-135380 |
| institution | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| issn | 1027-5495 |
| language | English |
| last_indexed | 2025-12-07T13:25:15Z |
| publishDate | 2012 |
| publisher | НТК «Інститут монокристалів» НАН України |
| record_format | dspace |
| spelling | Karbivskyy, V.L. Smolyak, S.S. Zagorodniy, Yu.A. Kasiyanenko, V.H. 2018-06-15T06:12:18Z 2018-06-15T06:12:18Z 2012 Electronic structure peculiarities of disordered Mn and Co diphosphates / V.L. Karbivskyy, S.S. Smolyak, Yu.A. Zagorodniy, V.H. Kasiyanenko // Functional Materials. — 2012. — Т. 19, № 4. — С. 459-463. — Бібліогр.: 6 назв. — англ. 1027-5495 https://nasplib.isofts.kiev.ua/handle/123456789/135380 Electronic structure peculiarities of disordered diphosphate —Mn₂₋ₓCoₓP₂O₇*5H₂O, with x = 0, 0.6, 1.0, 1.9, 2.0, were studied by XPS and X-ray emission spectroscopy. Substitution in the different degree of cobalt by manganese leads to a charge redistribu¬tion in the metal sublattice and results in increase of the chemical bond ionicity between oxygen anions and the metal cations. Such charge redistribution is responsible for forma¬tion of the states laying in the upper part of the valence band. en НТК «Інститут монокристалів» НАН України Functional Materials Characterization and properties Electronic structure peculiarities of disordered Mn and Co diphosphates Особливості електронної будови невпорядкованих дифосфатів Mn і Co Article published earlier |
| spellingShingle | Electronic structure peculiarities of disordered Mn and Co diphosphates Karbivskyy, V.L. Smolyak, S.S. Zagorodniy, Yu.A. Kasiyanenko, V.H. Characterization and properties |
| title | Electronic structure peculiarities of disordered Mn and Co diphosphates |
| title_alt | Особливості електронної будови невпорядкованих дифосфатів Mn і Co |
| title_full | Electronic structure peculiarities of disordered Mn and Co diphosphates |
| title_fullStr | Electronic structure peculiarities of disordered Mn and Co diphosphates |
| title_full_unstemmed | Electronic structure peculiarities of disordered Mn and Co diphosphates |
| title_short | Electronic structure peculiarities of disordered Mn and Co diphosphates |
| title_sort | electronic structure peculiarities of disordered mn and co diphosphates |
| topic | Characterization and properties |
| topic_facet | Characterization and properties |
| url | https://nasplib.isofts.kiev.ua/handle/123456789/135380 |
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