Electronic structure peculiarities of disordered Mn and Co diphosphates
Electronic structure peculiarities of disordered diphosphate —Mn₂₋ₓCoₓP₂O₇*5H₂O, with x = 0, 0.6, 1.0, 1.9, 2.0, were studied by XPS and X-ray emission spectroscopy. Substitution in the different degree of cobalt by manganese leads to a charge redistribu¬tion in the metal sublattice and results in i...
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| Опубліковано в: : | Functional Materials |
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| Дата: | 2012 |
| Автори: | , , , |
| Формат: | Стаття |
| Мова: | English |
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НТК «Інститут монокристалів» НАН України
2012
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| Онлайн доступ: | https://nasplib.isofts.kiev.ua/handle/123456789/135380 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Electronic structure peculiarities of disordered Mn and Co diphosphates / V.L. Karbivskyy, S.S. Smolyak, Yu.A. Zagorodniy, V.H. Kasiyanenko // Functional Materials. — 2012. — Т. 19, № 4. — С. 459-463. — Бібліогр.: 6 назв. — англ. |
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Karbivskyy, V.L. Smolyak, S.S. Zagorodniy, Yu.A. Kasiyanenko, V.H. 2018-06-15T06:12:18Z 2018-06-15T06:12:18Z 2012 Electronic structure peculiarities of disordered Mn and Co diphosphates / V.L. Karbivskyy, S.S. Smolyak, Yu.A. Zagorodniy, V.H. Kasiyanenko // Functional Materials. — 2012. — Т. 19, № 4. — С. 459-463. — Бібліогр.: 6 назв. — англ. 1027-5495 https://nasplib.isofts.kiev.ua/handle/123456789/135380 Electronic structure peculiarities of disordered diphosphate —Mn₂₋ₓCoₓP₂O₇*5H₂O, with x = 0, 0.6, 1.0, 1.9, 2.0, were studied by XPS and X-ray emission spectroscopy. Substitution in the different degree of cobalt by manganese leads to a charge redistribu¬tion in the metal sublattice and results in increase of the chemical bond ionicity between oxygen anions and the metal cations. Such charge redistribution is responsible for forma¬tion of the states laying in the upper part of the valence band. en НТК «Інститут монокристалів» НАН України Functional Materials Characterization and properties Electronic structure peculiarities of disordered Mn and Co diphosphates Особливості електронної будови невпорядкованих дифосфатів Mn і Co Article published earlier |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| title |
Electronic structure peculiarities of disordered Mn and Co diphosphates |
| spellingShingle |
Electronic structure peculiarities of disordered Mn and Co diphosphates Karbivskyy, V.L. Smolyak, S.S. Zagorodniy, Yu.A. Kasiyanenko, V.H. Characterization and properties |
| title_short |
Electronic structure peculiarities of disordered Mn and Co diphosphates |
| title_full |
Electronic structure peculiarities of disordered Mn and Co diphosphates |
| title_fullStr |
Electronic structure peculiarities of disordered Mn and Co diphosphates |
| title_full_unstemmed |
Electronic structure peculiarities of disordered Mn and Co diphosphates |
| title_sort |
electronic structure peculiarities of disordered mn and co diphosphates |
| author |
Karbivskyy, V.L. Smolyak, S.S. Zagorodniy, Yu.A. Kasiyanenko, V.H. |
| author_facet |
Karbivskyy, V.L. Smolyak, S.S. Zagorodniy, Yu.A. Kasiyanenko, V.H. |
| topic |
Characterization and properties |
| topic_facet |
Characterization and properties |
| publishDate |
2012 |
| language |
English |
| container_title |
Functional Materials |
| publisher |
НТК «Інститут монокристалів» НАН України |
| format |
Article |
| title_alt |
Особливості електронної будови невпорядкованих дифосфатів Mn і Co |
| description |
Electronic structure peculiarities of disordered diphosphate —Mn₂₋ₓCoₓP₂O₇*5H₂O, with x = 0, 0.6, 1.0, 1.9, 2.0, were studied by XPS and X-ray emission spectroscopy. Substitution in the different degree of cobalt by manganese leads to a charge redistribu¬tion in the metal sublattice and results in increase of the chemical bond ionicity between oxygen anions and the metal cations. Such charge redistribution is responsible for forma¬tion of the states laying in the upper part of the valence band.
|
| issn |
1027-5495 |
| url |
https://nasplib.isofts.kiev.ua/handle/123456789/135380 |
| citation_txt |
Electronic structure peculiarities of disordered Mn and Co diphosphates / V.L. Karbivskyy, S.S. Smolyak, Yu.A. Zagorodniy, V.H. Kasiyanenko // Functional Materials. — 2012. — Т. 19, № 4. — С. 459-463. — Бібліогр.: 6 назв. — англ. |
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