Electronic structure peculiarities of disordered Mn and Co diphosphates

• Published in: Functional Materials
• Date: 2012
• Main Authors: Karbivskyy, V.L., Smolyak, S.S., Zagorodniy, Yu.A., Kasiyanenko, V.H.
• Format: Article
• Language: English
• Published: НТК «Інститут монокристалів» НАН України 2012
• Subjects: Characterization and properties
• Online Access: https://nasplib.isofts.kiev.ua/handle/123456789/135380
• Journal Title: Digital Library of Periodicals of National Academy of Sciences of Ukraine
• Cite this: Electronic structure peculiarities of disordered Mn and Co diphosphates / V.L. Karbivskyy, S.S. Smolyak, Yu.A. Zagorodniy, V.H. Kasiyanenko // Functional Materials. — 2012. — Т. 19, № 4. — С. 459-463. — Бібліогр.: 6 назв. — англ.

Electronic structure peculiarities of disordered diphosphate —Mn₂₋ₓCoₓP₂O₇*5H₂O, with x = 0, 0.6, 1.0, 1.9, 2.0, were studied by XPS and X-ray emission spectroscopy. Substitution in the different degree of cobalt by manganese leads to a charge redistribu¬tion in the metal sublattice and results in i...