Formation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditions
This article studies the regularities of formation of isostructural to langbeinite phosphates from solutions in melts under crystallization conditions for K₂O-P₂O₅-M<m^>III₂O₃-SnO₂ (MIII - Fe, Cr) and K₂O-P₂O₅-LnF₃-SnO₂ (Ln - Y, REE) systems. Based on X-ray powder diffraction method the ph...
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| Опубліковано в: : | Functional Materials |
|---|---|
| Дата: | 2017 |
| Автори: | , , , |
| Формат: | Стаття |
| Мова: | Англійська |
| Опубліковано: |
НТК «Інститут монокристалів» НАН України
2017
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| Онлайн доступ: | https://nasplib.isofts.kiev.ua/handle/123456789/136747 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Formation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditions / I.V. Zatovsky, N.S. Slobodyanik, T.I. Ushchapivska, W. Han // Functional Materials. — 2017. — Т. 24, № 2. — С. 298-302. — Бібліогр.: 15 назв. — англ. |
Репозитарії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| _version_ | 1862696449990459392 |
|---|---|
| author | Zatovsky, I.V. Slobodyanik, N.S. Ushchapivska, T.I. Han, W. |
| author_facet | Zatovsky, I.V. Slobodyanik, N.S. Ushchapivska, T.I. Han, W. |
| citation_txt | Formation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditions / I.V. Zatovsky, N.S. Slobodyanik, T.I. Ushchapivska, W. Han // Functional Materials. — 2017. — Т. 24, № 2. — С. 298-302. — Бібліогр.: 15 назв. — англ. |
| collection | DSpace DC |
| container_title | Functional Materials |
| description | This article studies the regularities of formation of isostructural to langbeinite phosphates from solutions in melts under crystallization conditions for K₂O-P₂O₅-M<m^>III₂O₃-SnO₂ (MIII - Fe, Cr) and K₂O-P₂O₅-LnF₃-SnO₂ (Ln - Y, REE) systems. Based on X-ray powder diffraction method the phase composition of synthesized samples and lattice parameters have been determined for a number of new compounds with common composition K₂MIIISn(PO₄)₃. Analysis of obtained results shows that the crystallochemical criterion for formation of langbeinite-type framework on the basis of different multivalent metals is the difference in their ionic radii up to 35 %.
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| first_indexed | 2025-12-07T16:28:04Z |
| format | Article |
| fulltext | |
| id | nasplib_isofts_kiev_ua-123456789-136747 |
| institution | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| issn | 1027-5495 |
| language | English |
| last_indexed | 2025-12-07T16:28:04Z |
| publishDate | 2017 |
| publisher | НТК «Інститут монокристалів» НАН України |
| record_format | dspace |
| spelling | Zatovsky, I.V. Slobodyanik, N.S. Ushchapivska, T.I. Han, W. 2018-06-16T15:38:10Z 2018-06-16T15:38:10Z 2017 Formation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditions / I.V. Zatovsky, N.S. Slobodyanik, T.I. Ushchapivska, W. Han // Functional Materials. — 2017. — Т. 24, № 2. — С. 298-302. — Бібліогр.: 15 назв. — англ. 1027-5495 DOI: https://doi.org/10.15407/fm24.02.298 https://nasplib.isofts.kiev.ua/handle/123456789/136747 This article studies the regularities of formation of isostructural to langbeinite phosphates from solutions in melts under crystallization conditions for K₂O-P₂O₅-M<m^>III₂O₃-SnO₂ (MIII - Fe, Cr) and K₂O-P₂O₅-LnF₃-SnO₂ (Ln - Y, REE) systems. Based on X-ray powder diffraction method the phase composition of synthesized samples and lattice parameters have been determined for a number of new compounds with common composition K₂MIIISn(PO₄)₃. Analysis of obtained results shows that the crystallochemical criterion for formation of langbeinite-type framework on the basis of different multivalent metals is the difference in their ionic radii up to 35 %. en НТК «Інститут монокристалів» НАН України Functional Materials Technology Formation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditions Article published earlier |
| spellingShingle | Formation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditions Zatovsky, I.V. Slobodyanik, N.S. Ushchapivska, T.I. Han, W. Technology |
| title | Formation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditions |
| title_full | Formation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditions |
| title_fullStr | Formation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditions |
| title_full_unstemmed | Formation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditions |
| title_short | Formation of complex phosphates K₂MᴵᴵᴵSn(PO₄)₃ from solutions in melts under crystallization conditions |
| title_sort | formation of complex phosphates k₂mᴵᴵᴵsn(po₄)₃ from solutions in melts under crystallization conditions |
| topic | Technology |
| topic_facet | Technology |
| url | https://nasplib.isofts.kiev.ua/handle/123456789/136747 |
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