GdVO₄:Eu³⁺ nanoparticles - embedded CaCO₃ microspheres: synthesis and characterization

• Date: 2017
• Main Authors: Bespalova, I.I., Yefimova, S.L., Tkacheva, T.N., Hubenko, K.A., Sorokin, A.V., Mateychenko, P.V.
• Format: Article
• Language: English
• Published: НТК «Інститут монокристалів» НАН України 2017
• Series: Functional Materials
• Subjects: Characterization and properties
• Online Access: https://nasplib.isofts.kiev.ua/handle/123456789/136796
• Journal Title: Digital Library of Periodicals of National Academy of Sciences of Ukraine
• Cite this: GdVO₄:Eu³⁺ nanoparticles - embedded CaCO₃ microspheres: synthesis and characterization / I.I. Bespalova, S.L. Yefimova, T.N. Tkacheva, K.A. Hubenko, A.V. Sorokin, P.V. Mateychenko // Functional Materials. — 2017. — Т. 24, № 3. — С. 393-399. — Бібліогр.: 50 назв. — англ.

In present study, we report on synthesis of fluorescent GdVO₄:Eu³⁺ nanoparticle-embedded CaCO₃ microparticles (CaCO₃@GdVO₄:Eu³⁺) and their characterization. Synthesized CaCO₃@GdVO₄:Eu³⁺ microspheres are of vaterite polymorph and about 2 µm diameter with -12.80±0.82 mV zeta potential. The specific surface area of the CaCO₃@GdVO₄:Eu³⁺ microspheres and pore size distribution were analyzed by Brunauer-Emmett-Teller method. The microparticles was classified as macroporous ones with a wide distribution of pore sizes.The specific surface area for CaCO₃@GdVO₄:Eu³⁺ microspheres (Sbet = 25.2 m²/g) is higher than reported for CaCO₃ microparticles obtained without any additives. CaCO₃@GdVO₄:Eu³⁺ microspheres exhibit strong fluorescence both in a water solution and under fluorescent microscopy conditions that makes them attractive for bio-related application.