The alternative approach to the preparation of complex calcium phosphates and their characterization
In this paper a new approach to the preparation of complex calcium-containing phosphates using molten chlorides and nitrates of alkaline metals as fluxes was described. The main advantages of used technique for synthesis of double phosphates comparing with traditional methods (solid state reactions...
Saved in:
| Date: | 2017 |
|---|---|
| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
| Published: |
НТК «Інститут монокристалів» НАН України
2017
|
| Series: | Functional Materials |
| Subjects: | |
| Online Access: | https://nasplib.isofts.kiev.ua/handle/123456789/136812 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Journal Title: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Cite this: | The alternative approach to the preparation of complex calcium phosphates and their characterization / Ok. Livitska, N. Strutynska, Ol. Livitska, N. Slobodyanik // Functional Materials. — 2017. — Т. 24, № 3. — С. 457-562. — Бібліогр.: 42 назв. — англ. |
Institution
Digital Library of Periodicals of National Academy of Sciences of Ukraine| Summary: | In this paper a new approach to the preparation of complex calcium-containing phosphates using molten chlorides and nitrates of alkaline metals as fluxes was described. The main advantages of used technique for synthesis of double phosphates comparing with traditional methods (solid state reactions or crystallization of a high temperature self-flux) were discussed. It was found that the phase composition of obtained crystalline products depends on type of salt melts, nature of alkaline metals and type of initial components. Formation conditions for compounds MICaPO₄, MI₂CaP₂O₇ (MI - Na, K), Ca₂P₂O₇, Ca₂PO₄Cl and Ca₁₀(PO₄)₆Cl₂ were established. The synthesized phosphates were characterized using powder X-ray diffraction, Fourier transform infrared spectroscopy and optical microscopy. |
|---|