Experimental research on mechanical properties of desert sand steel-PVA fiber engineered cementitious composites

An orthogonal experimental design method involving five-factor and four-level is adopted for the mix design of Desert Sand Steel-PVA fiber ECC. The effect of each level on Mechanical properties of ECC and the difference of Mechanical properties between each level is analyzed. The influence of differ...

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Published in:Functional Materials
Date:2017
Main Authors: Che Jialing, Li Quanwei, Lee Minggin, Wang Dan
Format: Article
Language:English
Published: НТК «Інститут монокристалів» НАН України 2017
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Online Access:https://nasplib.isofts.kiev.ua/handle/123456789/136851
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Cite this:Experimental research on mechanical properties of desert sand steel-PVA fiber engineered cementitious composites / Che Jialing, Li Quanwei, Lee Minggin, Wang Dan // Functional Materials. — 2017. — Т. 24, № 4. — С. 584-592. — Бібліогр.: 15 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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spelling Che Jialing
Li Quanwei
Lee Minggin
Wang Dan
2018-06-16T16:57:40Z
2018-06-16T16:57:40Z
2017
Experimental research on mechanical properties of desert sand steel-PVA fiber engineered cementitious composites / Che Jialing, Li Quanwei, Lee Minggin, Wang Dan // Functional Materials. — 2017. — Т. 24, № 4. — С. 584-592. — Бібліогр.: 15 назв. — англ.
1027-5495
DOI: https://doi.org/10.15407/fm24.04.584
https://nasplib.isofts.kiev.ua/handle/123456789/136851
An orthogonal experimental design method involving five-factor and four-level is adopted for the mix design of Desert Sand Steel-PVA fiber ECC. The effect of each level on Mechanical properties of ECC and the difference of Mechanical properties between each level is analyzed. The influence of different experimental factors is discussed, which includes water-binder ratio, fly ash substitution rate, desert sand substitution rate, proportion of PVA fiber and proportion of steel fiber. The experimental results indicate that water-binder ratio and fly ash substitution rate are the most principal and significant influencing factors on the compressive strength of ECC, regardless of age. Steel fiber is conducive to development of splitting tensile strength; PVA fiber is conducive to the development of flexural strength. High strength ECC can be prepared when the desert sand substitution rate is high. As the raw material of ECC, river sand can be 90% replaced by desert sand.
en
НТК «Інститут монокристалів» НАН України
Functional Materials
Characterization and properties
Experimental research on mechanical properties of desert sand steel-PVA fiber engineered cementitious composites
Article
published earlier
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
title Experimental research on mechanical properties of desert sand steel-PVA fiber engineered cementitious composites
spellingShingle Experimental research on mechanical properties of desert sand steel-PVA fiber engineered cementitious composites
Che Jialing
Li Quanwei
Lee Minggin
Wang Dan
Characterization and properties
title_short Experimental research on mechanical properties of desert sand steel-PVA fiber engineered cementitious composites
title_full Experimental research on mechanical properties of desert sand steel-PVA fiber engineered cementitious composites
title_fullStr Experimental research on mechanical properties of desert sand steel-PVA fiber engineered cementitious composites
title_full_unstemmed Experimental research on mechanical properties of desert sand steel-PVA fiber engineered cementitious composites
title_sort experimental research on mechanical properties of desert sand steel-pva fiber engineered cementitious composites
author Che Jialing
Li Quanwei
Lee Minggin
Wang Dan
author_facet Che Jialing
Li Quanwei
Lee Minggin
Wang Dan
topic Characterization and properties
topic_facet Characterization and properties
publishDate 2017
language English
container_title Functional Materials
publisher НТК «Інститут монокристалів» НАН України
format Article
description An orthogonal experimental design method involving five-factor and four-level is adopted for the mix design of Desert Sand Steel-PVA fiber ECC. The effect of each level on Mechanical properties of ECC and the difference of Mechanical properties between each level is analyzed. The influence of different experimental factors is discussed, which includes water-binder ratio, fly ash substitution rate, desert sand substitution rate, proportion of PVA fiber and proportion of steel fiber. The experimental results indicate that water-binder ratio and fly ash substitution rate are the most principal and significant influencing factors on the compressive strength of ECC, regardless of age. Steel fiber is conducive to development of splitting tensile strength; PVA fiber is conducive to the development of flexural strength. High strength ECC can be prepared when the desert sand substitution rate is high. As the raw material of ECC, river sand can be 90% replaced by desert sand.
issn 1027-5495
url https://nasplib.isofts.kiev.ua/handle/123456789/136851
citation_txt Experimental research on mechanical properties of desert sand steel-PVA fiber engineered cementitious composites / Che Jialing, Li Quanwei, Lee Minggin, Wang Dan // Functional Materials. — 2017. — Т. 24, № 4. — С. 584-592. — Бібліогр.: 15 назв. — англ.
work_keys_str_mv AT chejialing experimentalresearchonmechanicalpropertiesofdesertsandsteelpvafiberengineeredcementitiouscomposites
AT liquanwei experimentalresearchonmechanicalpropertiesofdesertsandsteelpvafiberengineeredcementitiouscomposites
AT leeminggin experimentalresearchonmechanicalpropertiesofdesertsandsteelpvafiberengineeredcementitiouscomposites
AT wangdan experimentalresearchonmechanicalpropertiesofdesertsandsteelpvafiberengineeredcementitiouscomposites
first_indexed 2025-11-26T01:42:54Z
last_indexed 2025-11-26T01:42:54Z
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fulltext 584 Functional materials, 24, 4, 2017 ISSN 1027-5495. Functional Materials, 24, No.4 (2017), p. 584-592 doi:https://doi.org/10.15407/fm24.04.584 © 2017 — STC “Institute for Single Crystals” Experimental research on mechanical properties of desert sand steel-PVA fiber engineered cementitious composites Che Jialing1, Li Quanwei1, Lee Minggin2, Wang Dan1 1 School of Civil Engineering and Hyd raulic Engineering, Ningxia University, Yinchuan Ningxia, 750021, P.R.China 2Department of Civil Engineering, Chaoyang University of Technology, Taichung County, 41349, Taiwan Received August 23, 2017 An orthogonal experimental design method involving five-factor and four-level is adopted for the mix design of Desert Sand Steel-PVA fiber ECC. The effect of each level on Mechanical properties of ECC and the difference of Mechanical properties between each level is analyzed. The influence of different experimental factors is discussed, which includes water-binder ratio, fly ash substitution rate, desert sand substitution rate, proportion of PVA fiber and proportion of steel fiber. The experimental results indicate that water-binder ratio and fly ash substitution rate are the most principal and significant influencing factors on the compressive strength of ECC, regardless of age. Steel fiber is conducive to development of splitting tensile strength; PVA fiber is conducive to the development of flexural strength. High strength ECC can be prepared when the desert sand substitution rate is high. As the raw material of ECC, river sand can be 90% replaced by desert sand. Keywords: Desert sand, Engineered cementitious composites(ECC), Mechanical properties, Orthogonal experiment, PVA fiber, Steel fiber. Исследуется влияние различных факторов на свойства экологически чистого и экономически выгодного конструкционного строительного композитного материала (ККМ). Исследовалась смесь волоконной эмульсии Desert Sand Steel-PVA. Для исследований использовался метод ортогонального экспериментального проектирования с пятифакторным (соотношение вода-связующее, скорость замещения летучей золы, скорость замещения песка пустыни, доли волокна ПВА и доли стального волокна) и четырехуровневым испытанием на прочность. Экспериментальные результаты показывают, что соотношение воды и связующего материала, а также скорость замещивания летучей золы являются наиболее влияющими факторами на прочность на сжатие ККМ, независимо от срока его получения. Стальное волокно способствует развитию растягивающей силы расщепления; ПВА волокно способствует развитию прочности на изгиб. Высокопрочный ECC может быть приготовлен, при большой скорости замещения песка пустынию. В качестве сырья ККМ речной песок может быть заменен на 90% пустынным песком . Експериментальні дослідження механічних властивостей конструкційного композитного матеріалу Desert Sand Steel-PVA. Che Jialing, Li Quanwei, Lee Minggin, Wang Dan. Досліджується вплив різних чинників на властивості екологічно чистого та економічно вигідного конструкційного будівельного композитного матеріалу (ККП). Досліджувалася суміш волоконної емульсії Desert Sand Steel-PVA. Для досліджень використовувався метод ортогонального експериментального проектування з п’ятифакторна (співвідношення вода- Functional materials, 24, 34 2017 585 Che Jialing et al. / Experimental research on mechanical properties ... 1. Introduction Engineered Cementitious Composites (here- inafter referred to as ECC) was proposed in the last late century ECC is micromechanically designed composites with fiber as reinforce- ment material, cement as main base material. It features outstanding energy consuming ca- pacity, strain hardening and crack steady state development. ECC can effectively improve the seismic resistance of the structure [1], extend service life of the material [2]. Research on steel-PVA cementitious compos- ites show that addition of fly ash, increase of fiber proportion help multiple cracking [3.4]. PVA-ECC has outstanding property of peak delay [5]. The damage crack of PVA-ECC is less wide, which can be controlled within 100μm [2, 6], Harbin Insti- tute of Technology researched high fly ash pro- portion ECC, its 28d limit tensile strain is all above 3%, exhibiting outstanding strain-hard- ening property [7]. From the angle of sustain- ability of the environment, ECC consumes less resource, emits less pollution [8]. Adoption of ECC can increase compressive strength and tensile strength of the concrete test piece [9]. Experiments show that compressive strength of 4-day aged ECC can meet the strength re- quired by deck slab design, conducive to speed- ing up construction [10]. Using micromechani- cal design can achieve ideal performance of ECC [11]. Fly ash, water-binder ratio, fiber dis- perse condition all can influence tensile proper- ty of ECC [12, 13]. When steel fiber proportion is 2.0%, difficult dispersal and serious caking of steel fiber results strength of ECC lower than that of the test piece with steel fiber proportion 1,5% [14]. Large amount of non-renewable building material is consumed, so using a substitute for building material is of significance for sus- tainable development of the industry. Sand for building has limited reserve and cannot be regenerated within short term worldwide, while every continent has deserts of different size, and desert sand can partly substitute for river sand used for concrete, whose smaller grain size makes concrete inside more even, more compact. Currently, the thermal power is still the main electric source globally, nowhere can place a large amount of waste fly ash dis- charged from thermal power plants. Fly ash can substitute for cement to a certain extent, and improve performance of concrete, avoid waste pollution. Desert sand and fly ash are used in concrete as substitute material, saving resources and lowering cost. Desert sand steel- PVA fiber ECC prepared in this paper uses des- ert sand to substitute for part of river sand, fly ash to substitute for part of cement. 2. Experiment design 2.1. Experimental material Saima branded p.o.42.5 ordinary portland cement of Ningxia, China, its specific surface area is 339m2/kg, the chemical composition is shown in Table 1, the properties is shown in Table 2; for class I fly ash of Ningxia Lingwu Thermal Power Plant, water content is 0.4%, water demand ratio is 90%, fineness is 8.4%, loss on ignition is 3%, the chemical composi- tion is shown in Table 1; the desert sand is from Tengger Desert, with average grain size 0.23mm, fineness modulus is 0.7; for sieved river sand, max grain size is 1.18mm, fineness modulus is 2.1; PVA fiber is produced by Japan KURARAY, steel fiber selects copper plated micro wire steel fiber produced by Hengshui Fangde Silk Screen Products Factory, per- formance of fiber is shown in Table 3. Admix- ture is powdered high efficiency polycarboxylic acid water reducer, with water reducing rate 25%~30%. 2.2. Proportion of experiment The paper uses 5-factor 4-level (L1645) or- thogonal experiment, factors and levels is shown in Table 4. Mix design of orthogonal experiment is shown in Table 5. 2.3. Test piece preparation and experi- mental method In order to make PVA fiber and steel fibers disperse evenly without caking, steel fiber pre- mixing and PVA fiber after-mixing were adopt- ed. First mix and agitate river sand and desert sand for 1min, add cement and fly ash agitat- ing for 1 min, then add steel fiber agitating for 1min, add water and water reducer agitating for 2min, finally add PVA fiber agitating for 2min. After agitation cast a test piece and vibrate it сполучна, швидкість заміщення летючого попелу, швидкість заміщення піску пустелі, частки волокна ПВА і частки сталевого волокна) і чотирьохрівневим випробуванням на міцність. Експериментальні результати показують, що співвідношення води і сполучного матеріалу, а також швидкість замещіванія летючої золи є найбільш впливають факторами на міцність на стиск ККМ, незалежно від терміну його отримання. Сталеве волокно сприяє розвитку сили, що розтягує розщеплення; ПВА волокно сприяє розвитку міцності на вигин. Високоміцний ECC може бути приготований, при великій швидкості заміщення піску пустелі. В якості сировини ККМ річковий пісок може бути замінений на 90% пустельним піском. 586 Functional materials, 24, 4, 2017 Che Jialing et al. / Experimental research on mechanical properties ... Table 1. Chemical composition of ordinary portland cement and fly ash Chemical composition/% CaO SiO2 Al2O3 Fe2O3 SO3 MgO Na2O K2O Others Cement 60.24 21.22 5.05 3.26 2.67 0.97 0.73 0.50 5.36 Fly ash 3.16 53.80 24.60 9.32 0.42 1.52 0.28 0.82 6.08 Table 2. Properties of ordinary portland cement Properties Fineness /% Consistency water consumption /% initial setting time /min Final set- ting time /min Flexural strength /MPa compressive strength /MPa Value 4.4 26 130 180 9.0 55.6 Table 3. Performance of experimental fiber Type Length /mm Color Diameter /mm Tensile strength/MPa Modules of elasticity/GPa PVA fiber 12 white 0.04 1560 41 Steel fiber 13 yellow 0.2 >2850 210 Table 4. Factors and levels Factors Levels Water-binder ratio Fly ash substitute rate /% Desert sand substitute rate/% Proportion of pva fiber/% Proportion of steel fiber/% 1 0.19 15 0 0 0 2 0.24 30 30 0.4 0.4 3 0.29 45 60 0.8 0.8 4 0.34 60 90 1.2 1.2 Table 5. Mix design of orthogonal experiment Factors No. of specimens A. Water- binder ratio B. Fly ash sub- stitute rate/% C. Desert sand substitute rate/% D. Proportion of pva fiber/% E. Proportion of steel fiber/% 1 1 (0.19) 1 (15) 1 (0) 1 (0) 1 (0) 2 1 (0.19) 2 (30) 2 (30) 2 (0.4) 2 (0.4) 3 1 (0.19) 3 (45) 3 (60) 3 (0.8) 3 (0.8) 4 1 (0.19) 4 (60) 4 (90) 4 (1.2) 4 (1.2) 5 2 (0.24) 1 (15) 2 (30) 3 (0.8) 4 (1.2) 6 2 (0.24) 2 (30) 1 (0) 4 (1.2) 3 (0.8) 7 2 (0.24) 3 (45) 4 (90) 1 (0) 2 (0.4) 8 2 (0.24) 4 (60) 3 (60) 2 (0.4) 1 (0) 9 3 (0.29) 1 (15) 3 (60) 4 (1.2) 2 (0.4) 10 3 (0.29) 2 (30) 4 (90) 3 (0.8) 1 (0) 11 3 (0.29) 3 (45) 1 (0) 2 (0.4) 4 (1.2) 12 3 (0.29) 4 (60) 2 (30) 1 (0) 3 (0.8) 13 4 (0.34) 1 (15) 4 (90) 2 (0.4) 3 (0.8) 14 4 (0.34) 2 (30) 3 (60) 1 (0) 4 (1.2) 15 4 (0.34) 3 (45) 2 (30) 4 (1.2) 1 (0) 16 4 (0.34) 4 (60) 1 (0) 3 (0.8) 2 (0.4) Functional materials, 24, 34 2017 587 Che Jialing et al. / Experimental research on mechanical properties ... solid. Strip mould after 24h, being cured to 7d, 28d. After curing, dry the test piece and con- duct mechanical property experiment. Measure failure load on universal testing ma- chine, calculating compressive strength, split- ting tensile strength, flexural strength accord- ing to corresponding equation respectively. The compressive strength was measured by the 70.7mm ´ 70.7mm ´ 70.7mm cube speci- mens, the tensile strength was measured by the 100mm ´ 100mm ´ 100mm cube speci- mens, and the flexural strength was measured by 40mm ´ 40mm ´ 160mm prism specimens. 3. Experimental result and analysis Experimental results of 7d, 28d compres- sive strength and splitting tensile strength and 28d flexural strength are shown in Table 6. The purpose of this experiment is to study the effect of individual factors on the properties of ECC, and the combination of the interaction between the factors is complex, so the interaction be- tween factors is not discussed in this paper. 3.1. Intuitive analysis It is known from No. 3 and No.7 28d com- pressive strength in Table 6 that: When water-binder ratio is the lowest (0.19), fly ash substitution rate is 45%, when using high desert sand substitute (60%), we can still prepare high strength ECC with compressive strength above 75Mpa (No. 3); when water- binder ratio is low (0.24), even fly ash substi- tution rate is up to 45%, using extremely high desert sand substitution rate (90%), the com- pressive strength is still up to 60 Mpa (No. 7). 3.2. Range analysis Range analysis is shown in Table 7. The influence trends of each factor in the strength is shown in Figure 1. It is known from Table 7 and Figure 1 that: (1) As water-binder ratio increases, com- pressive strength, splitting tensile strength and flexural strength show decreasing trend; increase of the fly ash substitution rate will result in a decrease of 3 properties. As desert sand substitution rate increases, compressive strength and splitting tensile strength both increase first and decrease slowly then. Flex- ural strength shows the trend of slow decrease. When the desert sand substitution rate is 30%, compressive strength and splitting tensile strength reach the highest; as Proportion of PVA fiber increases, compressive strength and splitting tensile strength increases first and de- creases then, when the proportion is 0.8%, com- pressive strength and splitting tensile strength reach the highest; flexural strength increases with progressive increase of proportion of PVA fiber. As a proportion of steel fiber increases, compressive strength increases first and de- Table 6. Experimental results Properties No. of specimens 7d compressive strength/MPa 7d split- ting tensile strength/MPa 28d compres- sive strength/ MPa 28d split- ting tensile strength/MPa 28d flexural strength/MPa 1 59.47 12.33 81.58 15.61 13.19 2 69.89 26.71 94.07 23.45 14.27 3 56.21 21.49 75.08 29.84 20.86 4 33.42 25.69 52.87 24.46 17.25 5 75.04 32.14 87.43 37.67 24.54 6 56.58 19.24 71.85 20.25 22.9 7 46.06 15.18 60.67 18.01 7.60 8 41.73 12.11 47.55 8.58 5.24 9 51.79 18.29 61.16 20.92 15.66 10 42.41 13.15 55.26 14.86 10.16 11 40.11 14.76 56.07 27.73 15.47 12 23.82 8.21 36.17 14.03 5.99 13 44.45 14.70 55.08 16.81 9.48 14 34.46 13.77 53.92 20.97 11.15 15 28.55 9.81 39.88 13.65 13.83 16 23.38 7.95 36.18 11.75 10.02 588 Functional materials, 24, 4, 2017 Che Jialing et al. / Experimental research on mechanical properties ... creases then, splitting tensile strength and flexural strength show an increasing trend. (2) For 7d compressive strength, ranking of every influencing factors is: fly ash substitution rate (B)> water-binder ratio (A)> Proportion of PVA fiber(D) > desert sand substitute (C) > Proportion of steel fiber(E), the better combina- tion of condition is A2B1C2D3E2. For 28d com- pressive strength, ranking of every influencing factors is: water-binder ratio (A) > fly ash sub- stitution rate (B) >desert sand substitute (C) > Proportion of PVA fiber(D) >Proportion of steel fiber(E), the better combination of condition is A1B1C2D3E2. For 7d splitting tensile strength, ranking of every influencing factors is: water- binder ratio (A) >Proportion of steel fiber(E) > Proportion of PVA fiber(D) > fly ash substitution rate (B) >desert sand substitute (C), the bet- ter combination of condition is A1B1C2D3E4. For 28d splitting tensile strength, ranking of every influencing factors is: Proportion of steel fiber(E) >fly ash substitution rate (B) >water- binder ratio (A)>Proportion of PVA fiber(D) >desert sand substitute (C), the better combi- nation of condition is A1B1C2D3E4. For 28d flexural strength, ranking of every influencing factors is: Proportion of PVA fiber(D) > Propor- tion of steel fiber(E) >fly ash substitution rate (B)>water-binder ratio (A) >desert sand substi- tute (C), the better combination of condition is A1B1C1D4E4. (3) The influence of water-binder ratio and fly ash substitution rate of compressive strength is especially significant; 7d splitting tensile strength is influenced by water-binder ratio most; 28d splitting tensile strength is influenced by Proportion of steel fiber most; Figure 1. Influence trends of each factor in the strength: (a) 7d compressive strength; (b) 7d splitting tensile strength; (c) 28d compressive strength; (d) 28d splitting tensile strength; (e) 28d flexural strength. Functional materials, 24, 34 2017 589 Che Jialing et al. / Experimental research on mechanical properties ... Proportion of PVA fiber influences flexural strength most. (4) According to integrated balance method, better combination of conditions is determined as A1B1C2D3E4. 3.3. Variance analysis Variance analysis is shown in Table 8. Tak- ing into account the four-level and five-factor orthogonal test, in the variance analysis, the factor whose mean square is the smallest is considered as error to calculate the value of F. It is known from Table 8 that: –According to mean square value, rank sig- nificance of influence of every factor on mechan- ical property from large to small, for splitting tensile strength, flexural strength, 7d compres- sive strength, the ranking is in accordance with range analysis; for 28d compressive strength, ranking of influence of every factors is: water- binder ratio (A) >fly ash substitution rate (B) >Proportion of PVA fiber(D) >desert sand sub- stitute (C) >Proportion of steel fiber(E), slightly different from range analysis. – Water-binder ratio (A) and fly ash substitu- tion rate (B) influence 7d compressive strength highly significantly (α = 0.01), influence 28d compressive strength moderately significant (α = 0.05); Proportion of steel fiber(E) influences 28d splitting tensile strength significantly. Variation of desert sand substitute (C) does not influence every performance obviously. 4. Failure modes of specimens 4.1. Compression failure The specimen without fiber often breaks unexpectedly, with the larger piece falling off as shown in Figure 2 (a). The specimen with only steel fiber has small piece falling off, with relatively complete contour, the surface shows several cracks with certain width, as shown in Table 7. Range analysis Factors Properties A. Water-binder ratio B. Fly ash substi- tution rate/% C. Desert sand substitution rate/% D. Proportion of pva fiber/% E. Proportion of steel fiber/% 7d compressive strength K1 54.75 57.69 44.89 40.95 43.04 K2 54.85 50.84 49.33 49.05 47.78 K3 39.53 42.73 46.05 49.26 45.27 K4 32.71 30.59 41.59 42.59 45.76 R 22.14 27.10 7.74 8.31 4.74 7d splitting ten- sile strength K1 21.56 19.37 13.57 12.37 11.85 K2 19.67 18.22 19.22 17.07 17.03 K3 13.60 15.31 16.42 18.68 15.91 K4 11.56 13.49 17.18 18.26 21.59 R 10.00 5.88 5.65 6.31 9.74 28d compres- sive strength K1 75.90 71.31 61.42 58.09 56.07 K2 66.88 68.78 64.39 63.19 63.02 K3 52.17 57.93 59.43 63.49 59.55 K4 46.27 43.19 55.97 56.44 62.57 R 29.63 28.12 8.42 7.05 6.95 28d splitting tensile strength K1 23.34 22.75 18.84 17.16 13.18 K2 21.13 19.88 22.20 19.14 18.53 K3 19.39 22.31 20.08 23.53 20.23 K4 15.80 14.71 18.54 19.82 27.71 R 7.54 8.04 3.66 6.37 14.53 28d flexural strength K1 16.39 15.72 15.40 9.48 10.61 K2 15.07 14.62 14.66 11.12 11.89 K3 11.82 14.44 13.23 16.40 14.81 K4 11.12 9.63 11.12 17.41 17.10 R 5.27 6.09 4.28 7.93 6.49 590 Functional materials, 24, 4, 2017 Che Jialing et al. / Experimental research on mechanical properties ... Figure 2(b). The specimen with steel-PVA fiber has many micro cracks in the surface, with al- most nothing falling off in the surface, keeping good integrity, as shown in Figure 2(c), with cracks marked with marker pen. 4.2 Splitting failure The specimen without fiber will suddenly split with a “Bang” under max load, totally breaking, as shown in Figure 3(a). The speci- men with only steel fiber will form several wider main cracks, and the specimen is still linked together, as shown in Figure 3(b). The specimen with steel-PVA fiber forms 1 or two thinner main cracks and several micro cracks, failure mark in the surface is not apparent, as shown in Figure 3(c). Table 8. Variance analysis Properties Variance origin Square Sum degree of freedom Mean square F Critical value 7d com- pressive strength A SA=1488.698 3 496.233 32.746*** F0.01 (3, 3) =29.5 B SB=1628.132 3 542.711 35.814*** F0.05 (3, 3) =9.3 C SC=122.519 3 40.840 2.695 F0.1 (3, 3) =5.4 D SD=223.502 3 74.501 4.916 — E SE= 45.461 3 15.154 1.000 — Error Se= 45.461 3 15.154 — — Total ST=3508.311 15 — — — 7d split- ting tensile strength A SA=273.493 3 91.164 4.168 F0.01 (3, 3) =29.5 B SB=86.391 3 28.797 1.317 F0.05 (3, 3) =9.3 C SC=65.611 3 21.870 1.000 F0.1 (3, 3) =5.4 D SD=100.707 3 33.569 1.535 — E SE= 192.503 3 64.168 2.934 — Error Se= 65.611 3 21.870 — — Total ST=718.704 15 — — — 28d com- pressive strength A SA=2199.000 3 733.000 17.707** F0.01 (3, 3) =29.5 B SB=1965.632 3 655.211 15.828** F0.05 (3, 3) =9.3 C SC=149.889 3 49.963 1.207 F0.1 (3, 3) =5.4 D SD=153.330 3 51.110 1.235 — E SE= 124.187 3 41.396 1.000 — Error Se= 124.187 3 41.396 — — Total ST=4592.038 15 — — — 28d split- ting tensile strength A SA=121.824 3 40.608 3.661 F0.01 (3, 3) =29.5 B SB=163.682 3 54.561 4.919 F0.05 (3, 3) =9.3 C SC=33.274 3 11.091 1.000 F0.1 (3, 3) =5.4 D SD=85.166 3 28.389 2.560 — E SE= 432.651 3 144.217 13.003** — Error Se= 33.274 3 11.091 — — Total ST=836.597 15 — — — 28d flexural strength A SA=77.111 3 25.704 1.816 F0.01 (3, 3) =29.5 B SB=88.122 3 29.374 2.075 F0.05 (3, 3) =9.3 C SC=42.468 3 14.156 1.000 F0.1 (3, 3) =5.4 D SD=181.829 3 60.610 4.282 — E SE= 102.513 3 34.171 2.414 — Error Se= 42.468 3 14.156 — — Total ST=492.043 15 — — — NOTE: *** Significant at α level of 0.01;** Significant at α level of 0.05. Functional materials, 24, 34 2017 591 Che Jialing et al. / Experimental research on mechanical properties ... 4.3 Flexural failure The specimen without fiber gives out crisp sound of breaking when failing, the test piece is bent to two halves totally, as shown in Fig- ure 4(a). The test specimen with only steel fiber forms a wider crack in tensile area, the com- pressive area is still linked together, as shown in Figure 4(b). The specimen with steel-PVA fiber breaks to smaller cracks in compressive area, with relatively integrated form, as shown in Figure 4(c). 4.4 Cause analysis Test pieces with different type of fiber have different failure modes(There is no significant difference between specimens with only PVA fi- ber and specimens with steel-PVA fiber, so the failure mode of a specimen with only PVA fiber is not presented in the text). Two kinds of fiber used in the experiment are different greatly in size of the diameter, playing bridging role in different scale. PVA fibers mainly controls micro crack at an early stage of bearing load, steel fiber mainly controls macro crack. The test piece without fiber will generate a fragile burst failure; steel fiber ECC typically produces several wider main cracks when it fails; steel- PVA fiber ECC will produce many micro cracks when it fails, the form is damaged less, failure is slow, showing better ductility. 5. Conclusion Using inexhaustible desert sand and indus- trial waste fly ash, through orthogonal experi- ment, this paper mainly researches influence trend of 5 factors, including water-binder ratio, fly ash substitution rate, desert sand substitu- tion rate, proportion of PVA fiber, and propor- tion of steel fiber on ECC strengths, in order to find main factor influencing strength. Ac- cording to failure mode of test pieces, the role Figure 2. Compression failure modes. (a) Specimen without fiber (b) Specimen with only steel fiber (c) Specimen with steel-PVA fiber. Fig. 3. Splitting failure modes. (a) Specimen without fiber, (b) Specimen with only steel fiber, (c) Specimen with steel-PVA fiber. Fig. 4. Flexural failure modes. (a) Specimen without fiber, (b) Specimen with only steel fiber, (c) Specimen with steel-PVA fiber. 592 Functional materials, 24, 4, 2017 Che Jialing et al. / Experimental research on mechanical properties ... played in desert sand ECC by different fiber is analyzed. And it is concluded that: – When water-binder ratio is low, even if adopting high fly ash substitute and adding large amount of desert sand, high strength ECC can still be prepared, which is of significance for desert sand ECC at key location of high rise anti-seismic structure. – According to integrated balance method, finalized better condition of factor combination is A1B1C2D3E4, namely water-binder ratio is 0.19, fly ash substitution rate is 15%, the des- ert sand substitution rate is 30%, proportion of PVA fiber is 0.8%, proportion of steel fiber is 1.2%. –Water-binder ratio and fly ash substitu- tion rate influence compressive strength highly significant (a = 0.01), but low water-binder ra- tio and fly ash substitution rate result in even larger compressive strength; proportion of steel fibers significantly (a = 0.05) influences 28d splitting tensile strength, and steel fiber is conducive to development of splitting tensile strength; PVA fiber is conducive to the develop- ment of flexural strength. – Desert sand substitution rate does not sig- nificantly influence every mechanical proper- ties, but appropriate desert sand substitution rate can improve ECC property to a certain de- gree. In addition, max desert sand substitute in the experiment has been up to 90%, and the experimental group adopting 90% desert sand substitution rate does not decrease obviously in compressive strength, splitting tensile strength compared with the experimental group without desert sand, but flexural strength decreases to some extent. So it is inferred that as raw ma- terial of ECC, desert sand can further totally substitute for river sand. – PVA fiber enhances ductility of desert sand ECC, making the failure process of test piece failure intend to slow, conducive to multi- crack development of failure. Acknowledgements This work was financially supported by the National Natural Science Foundation of China with No. 51408328. References 1. V. C. Li, D.K. Mishra. A.E. Naaman, et al, Adv. Cement Based Mater., 1, 142, 1994. 2. V. C. Li, J. Adv. Conc. Techn., 1, 215,2003. 3. S. F. U. Ahmed, M. Maalej, P. Paramasivam, J. Ferrocement, 33, 172, 2003. 4. S. F. U. Ahmed, M. Maalej, P. Paramasivam, Constr. Building Mater., 21, 1088, 2007. 5. G. Fischer, V. C. Li, Struct. J., 99, 781, 2002 6. Xu Shilang, Cai Xinhua, Acta Mater. Compos. Sinica, 27, 177, 2010. 7. Y. Zhu, Y. Yang, Y. Yao, Constr. Building Ma- ter., 36, 1076, 2012. 8. H. Zhang, M.D. Lepech, G.A. Keoleian, et al, J. Infrastruct. Syst., 16, 299, 2009. 9. M. Şahmaran, V. C. Li, Structures Congress 2009: Don’t Mess with Structural Engineers: Expanding Our Role., 1-13, 2009. 10. M.D. Lepech, V. C. Li, Mater. Struct., 42, 1185, 2009. 11. V. C. Li, Int. J.Concrete Struct.Mater., 6, 135, 2012. 12. K. Sirijaroonchai, S. El-Tawil, G. Parra-Mon- tesinos, Cement Concrete Comp, 32, 62, 2010. 13. M. Li, V.C. Li, Mater. Struct., 46, 405, 2013. 14. Z. Zhang, S. Qian, H. Ma, Constr.Building Ma- ter., 52, 17, 2014.