Electron-conformational rearrangement in nanocomposites films of poly-N-epoxypropylcarbazole with fullerenes C₆₀
Optical absorption spectra, optical conductivity, refractive index n, extinction coefficient k and photoluminescence in nanocomposite films of poly-N-epoxypropylcarbazole (PEPC) with 0,7; 1,35; 2,5 and 4 wt.% of C₆₀ molecules were studied. Substantial restructuring of these spectra with changing the...
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| Published in: | Functional Materials |
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| Date: | 2017 |
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| Format: | Article |
| Language: | English |
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НТК «Інститут монокристалів» НАН України
2017
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| Online Access: | https://nasplib.isofts.kiev.ua/handle/123456789/136863 |
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| Journal Title: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Cite this: | Electron-conformational rearrangement in nanocomposites films of poly-N-epoxypropylcarbazole with fullerenes C₆₀ / O.P. Olasyuk, O.P. Dmytrenko, M.P. Kulish, M.A. Zabolotnyy, H.Y. Borodina, T.O. Busko // Functional Materials. — 2017. — Т. 24, № 4. — С. 563-571. — Бібліогр.: 18 назв. — англ. |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine| _version_ | 1862712928342376448 |
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| author | Olasyuk, O.P. Dmytrenko, O.P. Kulish, M.P. Zabolotnyy, M.A. Borodina, H.Y. Busko, T.O. |
| author_facet | Olasyuk, O.P. Dmytrenko, O.P. Kulish, M.P. Zabolotnyy, M.A. Borodina, H.Y. Busko, T.O. |
| citation_txt | Electron-conformational rearrangement in nanocomposites films of poly-N-epoxypropylcarbazole with fullerenes C₆₀ / O.P. Olasyuk, O.P. Dmytrenko, M.P. Kulish, M.A. Zabolotnyy, H.Y. Borodina, T.O. Busko // Functional Materials. — 2017. — Т. 24, № 4. — С. 563-571. — Бібліогр.: 18 назв. — англ. |
| collection | DSpace DC |
| container_title | Functional Materials |
| description | Optical absorption spectra, optical conductivity, refractive index n, extinction coefficient k and photoluminescence in nanocomposite films of poly-N-epoxypropylcarbazole (PEPC) with 0,7; 1,35; 2,5 and 4 wt.% of C₆₀ molecules were studied. Substantial restructuring of these spectra with changing the fullerene C₆₀ content was established not only in the intrinsic absorption, but also within the energy gap. Reducing the energy distance between states S₁ and T₁ with increasing concentration of C₆₀ molecules was showed, as well as the appearance of additional broad structureless bands with a maximum near 700 nm in the long-wave photoluminescence spectrum. Restructuring of the spectra is associated with electron-conformational changes caused by appearance of the donor-acceptor interaction between components in the films PEPC-C₆₀ due to formation of the complexes with charge transfer (CCT) in them.
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| first_indexed | 2025-12-07T17:40:24Z |
| format | Article |
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| id | nasplib_isofts_kiev_ua-123456789-136863 |
| institution | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| issn | 1027-5495 |
| language | English |
| last_indexed | 2025-12-07T17:40:24Z |
| publishDate | 2017 |
| publisher | НТК «Інститут монокристалів» НАН України |
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| spelling | Olasyuk, O.P. Dmytrenko, O.P. Kulish, M.P. Zabolotnyy, M.A. Borodina, H.Y. Busko, T.O. 2018-06-16T17:07:20Z 2018-06-16T17:07:20Z 2017 Electron-conformational rearrangement in nanocomposites films of poly-N-epoxypropylcarbazole with fullerenes C₆₀ / O.P. Olasyuk, O.P. Dmytrenko, M.P. Kulish, M.A. Zabolotnyy, H.Y. Borodina, T.O. Busko // Functional Materials. — 2017. — Т. 24, № 4. — С. 563-571. — Бібліогр.: 18 назв. — англ. 1027-5495 DOI: https://doi.org/10.15407/fm24.04.563 https://nasplib.isofts.kiev.ua/handle/123456789/136863 Optical absorption spectra, optical conductivity, refractive index n, extinction coefficient k and photoluminescence in nanocomposite films of poly-N-epoxypropylcarbazole (PEPC) with 0,7; 1,35; 2,5 and 4 wt.% of C₆₀ molecules were studied. Substantial restructuring of these spectra with changing the fullerene C₆₀ content was established not only in the intrinsic absorption, but also within the energy gap. Reducing the energy distance between states S₁ and T₁ with increasing concentration of C₆₀ molecules was showed, as well as the appearance of additional broad structureless bands with a maximum near 700 nm in the long-wave photoluminescence spectrum. Restructuring of the spectra is associated with electron-conformational changes caused by appearance of the donor-acceptor interaction between components in the films PEPC-C₆₀ due to formation of the complexes with charge transfer (CCT) in them. en НТК «Інститут монокристалів» НАН України Functional Materials Characterization and properties Electron-conformational rearrangement in nanocomposites films of poly-N-epoxypropylcarbazole with fullerenes C₆₀ Article published earlier |
| spellingShingle | Electron-conformational rearrangement in nanocomposites films of poly-N-epoxypropylcarbazole with fullerenes C₆₀ Olasyuk, O.P. Dmytrenko, O.P. Kulish, M.P. Zabolotnyy, M.A. Borodina, H.Y. Busko, T.O. Characterization and properties |
| title | Electron-conformational rearrangement in nanocomposites films of poly-N-epoxypropylcarbazole with fullerenes C₆₀ |
| title_full | Electron-conformational rearrangement in nanocomposites films of poly-N-epoxypropylcarbazole with fullerenes C₆₀ |
| title_fullStr | Electron-conformational rearrangement in nanocomposites films of poly-N-epoxypropylcarbazole with fullerenes C₆₀ |
| title_full_unstemmed | Electron-conformational rearrangement in nanocomposites films of poly-N-epoxypropylcarbazole with fullerenes C₆₀ |
| title_short | Electron-conformational rearrangement in nanocomposites films of poly-N-epoxypropylcarbazole with fullerenes C₆₀ |
| title_sort | electron-conformational rearrangement in nanocomposites films of poly-n-epoxypropylcarbazole with fullerenes c₆₀ |
| topic | Characterization and properties |
| topic_facet | Characterization and properties |
| url | https://nasplib.isofts.kiev.ua/handle/123456789/136863 |
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