Phosphorylated thiacalixarenes as molecular receptors for QCM sensors of volatile compounds

Phosphorylated thiacalixarenes as molecular receptors for QCM sensors of volatile compounds

Sorption of volatile organic compounds and ammonia by thin solid films of phosphorylated thiacalixarenes was investigated by the quartz crystal microbalance (QCM), X-ray crystallography and molecular modeling methods The interfacial sorption depends on the number and position (upper or lower rim) of...

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Veröffentlicht in:Functional Materials
Datum:2017
Hauptverfasser: Kazantseva, Z.I., Koshets, I.A., Belyaev, A.E., Ryabitskii, A.B., Kharchenko, S.G., Drapailo, A.B., Kalchenko, V.I., Shishkina, S.V., Shishkin, O.V.
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Sprache:English
Veröffentlicht: НТК «Інститут монокристалів» НАН України 2017
Schlagworte:
Characterization and properties
Online Zugang:https://nasplib.isofts.kiev.ua/handle/123456789/136874
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Zitieren:Phosphorylated thiacalixarenes as molecular receptors for QCM sensors of volatile compounds / Z.I. Kazantseva, I.A. Koshets, A.E. Belyaev, A.B. Ryabitskii, S.G. Kharchenko, A.B. Drapailo, V.I. Kalchenko, S.V. Shishkina, O.V. Shishkin // Functional Materials. — 2017. — Т. 24, № 4. — С. 599-606. — Бібліогр.: 37 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
id nasplib_isofts_kiev_ua-123456789-136874
record_format dspace
spelling Kazantseva, Z.I.
Koshets, I.A.
Belyaev, A.E.
Ryabitskii, A.B.
Kharchenko, S.G.
Drapailo, A.B.
Kalchenko, V.I.
Shishkina, S.V.
Shishkin, O.V.
2018-06-16T17:13:39Z
2018-06-16T17:13:39Z
2017
Phosphorylated thiacalixarenes as molecular receptors for QCM sensors of volatile compounds / Z.I. Kazantseva, I.A. Koshets, A.E. Belyaev, A.B. Ryabitskii, S.G. Kharchenko, A.B. Drapailo, V.I. Kalchenko, S.V. Shishkina, O.V. Shishkin // Functional Materials. — 2017. — Т. 24, № 4. — С. 599-606. — Бібліогр.: 37 назв. — англ.
1027-5495
DOI: https://doi.org/10.15407/fm24.04.599
https://nasplib.isofts.kiev.ua/handle/123456789/136874
Sorption of volatile organic compounds and ammonia by thin solid films of phosphorylated thiacalixarenes was investigated by the quartz crystal microbalance (QCM), X-ray crystallography and molecular modeling methods The interfacial sorption depends on the number and position (upper or lower rim) of P=O groups on the macrocyclic skeleton, the electronic nature of the substituents at the phosphorus atom. At low concentrations of the analytes their sorption occurs according to the Langmuir isotherm due to specific supramolecular interactions with receptor centers of the thiacalixarenes. The analytes may form either the Host-Guest inclusion complexes stabilized by C-H...π interactions, or extracavity complexes stabilized by hydrogen bonds with oxygen atoms of the peripheral P=O groups. At high concentrations, when the thiacalixarene receptor centers are occupied by the analytes, further sorption occurs nonspecifically according to the linear Henry isotherm due to inclusion of the analytes in voids of the crystal structure of the thiacalixarenes.
en
НТК «Інститут монокристалів» НАН України
Functional Materials
Characterization and properties
Phosphorylated thiacalixarenes as molecular receptors for QCM sensors of volatile compounds
Article
published earlier
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
title Phosphorylated thiacalixarenes as molecular receptors for QCM sensors of volatile compounds
spellingShingle Phosphorylated thiacalixarenes as molecular receptors for QCM sensors of volatile compounds
Kazantseva, Z.I.
Koshets, I.A.
Belyaev, A.E.
Ryabitskii, A.B.
Kharchenko, S.G.
Drapailo, A.B.
Kalchenko, V.I.
Shishkina, S.V.
Shishkin, O.V.
Characterization and properties
title_short Phosphorylated thiacalixarenes as molecular receptors for QCM sensors of volatile compounds
title_full Phosphorylated thiacalixarenes as molecular receptors for QCM sensors of volatile compounds
title_fullStr Phosphorylated thiacalixarenes as molecular receptors for QCM sensors of volatile compounds
title_full_unstemmed Phosphorylated thiacalixarenes as molecular receptors for QCM sensors of volatile compounds
title_sort phosphorylated thiacalixarenes as molecular receptors for qcm sensors of volatile compounds
author Kazantseva, Z.I.
Koshets, I.A.
Belyaev, A.E.
Ryabitskii, A.B.
Kharchenko, S.G.
Drapailo, A.B.
Kalchenko, V.I.
Shishkina, S.V.
Shishkin, O.V.
author_facet Kazantseva, Z.I.
Koshets, I.A.
Belyaev, A.E.
Ryabitskii, A.B.
Kharchenko, S.G.
Drapailo, A.B.
Kalchenko, V.I.
Shishkina, S.V.
Shishkin, O.V.
topic Characterization and properties
topic_facet Characterization and properties
publishDate 2017
language English
container_title Functional Materials
publisher НТК «Інститут монокристалів» НАН України
format Article
description Sorption of volatile organic compounds and ammonia by thin solid films of phosphorylated thiacalixarenes was investigated by the quartz crystal microbalance (QCM), X-ray crystallography and molecular modeling methods The interfacial sorption depends on the number and position (upper or lower rim) of P=O groups on the macrocyclic skeleton, the electronic nature of the substituents at the phosphorus atom. At low concentrations of the analytes their sorption occurs according to the Langmuir isotherm due to specific supramolecular interactions with receptor centers of the thiacalixarenes. The analytes may form either the Host-Guest inclusion complexes stabilized by C-H...π interactions, or extracavity complexes stabilized by hydrogen bonds with oxygen atoms of the peripheral P=O groups. At high concentrations, when the thiacalixarene receptor centers are occupied by the analytes, further sorption occurs nonspecifically according to the linear Henry isotherm due to inclusion of the analytes in voids of the crystal structure of the thiacalixarenes.
issn 1027-5495
url https://nasplib.isofts.kiev.ua/handle/123456789/136874
citation_txt Phosphorylated thiacalixarenes as molecular receptors for QCM sensors of volatile compounds / Z.I. Kazantseva, I.A. Koshets, A.E. Belyaev, A.B. Ryabitskii, S.G. Kharchenko, A.B. Drapailo, V.I. Kalchenko, S.V. Shishkina, O.V. Shishkin // Functional Materials. — 2017. — Т. 24, № 4. — С. 599-606. — Бібліогр.: 37 назв. — англ.
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first_indexed 2025-12-07T15:26:00Z
last_indexed 2025-12-07T15:26:00Z
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