Electron structure of apatite-like compounds with isomorphic substitution in tetrahedral positions

• Published in: Functional Materials
• Date: 2005
• Main Authors: Shpak, A.P., Karbovskii, V.L., Kurgan, N.A., Getman, E.I., Senkevich, A.I., Marchenko, V.I.
• Format: Article
• Language: English
• Published: НТК «Інститут монокристалів» НАН України 2005
• Online Access: https://nasplib.isofts.kiev.ua/handle/123456789/138885
• Journal Title: Digital Library of Periodicals of National Academy of Sciences of Ukraine
• Cite this: Electron structure of apatite-like compounds with isomorphic substitution in tetrahedral positions / A.P. Shpak, V.L. Karbovskii, N.A. Kurgan, E.I. Getman, A.I. Senkevich, V.I. Marchenko // Functional Materials. — 2005. — Т. 12, № 4. — С. 695-699. — Бібліогр.: 8 назв. — англ.

Effect of isomorphic anionic substitutions in the apatite-like calcium structures on their electron structure has been investigated. Changes in the electron subsystem of the first synthesized compounds Са₁₀(РО₄)₆-ₓ(VО₄)ₓ(М₂) (where М = F⁻,СI⁻, х - 0, 1, 3, 5, 6) caused by isomorphic anionic subs...