Formation of La-containing microcrystals in KCl and NaCl matrices

• Published in: Functional Materials
• Date: 2009
• Main Authors: Demkiv, T., Vistovskyy, V., Savchyn, P., Stryganyuk, G., Voloshinovskii, A., Demkiv, L.
• Format: Article
• Language: English
• Published: НТК «Інститут монокристалів» НАН України 2009
• Subjects: Characterization and properties
• Online Access: https://nasplib.isofts.kiev.ua/handle/123456789/138897
• Journal Title: Digital Library of Periodicals of National Academy of Sciences of Ukraine
• Cite this: Formation of La-containing microcrystals in KCl and NaCl matrices // T. Demkiv, V. Vistovskyy, P. Savchyn, G. Stryganyuk, A. Voloshinovskii, L. Demkiv // Functional Materials. — 2009. — Т. 16, № 3. — С. 225-229. — Бібліогр.: 12 назв. — англ.

The mechanism of the K₂LaCl₅ and LaCl₃ aggregate formation in KCl and NaCl matrices as a result of long-term annealing is discussed. Thermodynamic analysis of formation conditions of such aggregates has been performed. The influence of diffusion processes and the elastic deformation of aggregates by...