Peculiarities of thermal solid-phase transformations of hydrogenphosphates Co(II)-Mn(II)
Peculiarities of thermal solid-phase transformations of Co₁₋xMnxHPO₄·1.5 H₂O (0 ≤ x ≤ 0.45), which accompanying the formation of a final product of thermolysis - anhydrous diphosphate solid solution with composition β-(Co₁₋xMnx)₂P₂O₇ (0 < x le; 0.45) are established. It is shown that low-temp...
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| Veröffentlicht in: | Functional Materials |
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| Datum: | 2018 |
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| Format: | Artikel |
| Sprache: | Englisch |
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НТК «Інститут монокристалів» НАН України
2018
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| Online Zugang: | https://nasplib.isofts.kiev.ua/handle/123456789/154445 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Zitieren: | Peculiarities of thermal solid-phase transformations of hydrogenphosphates Co(II)-Mn(II) / N.M. Antraptseva, N.V. Solod, R.S. Zhyla // Functional Materials. — 2018. — Т. 25, № 1. — С. 151-157. — Бібліогр.: 14 назв. — англ. |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine| _version_ | 1862554687449858048 |
|---|---|
| author | Antraptseva, N.M. Solod, N.V. Zhyla, R.S. |
| author_facet | Antraptseva, N.M. Solod, N.V. Zhyla, R.S. |
| citation_txt | Peculiarities of thermal solid-phase transformations of hydrogenphosphates Co(II)-Mn(II) / N.M. Antraptseva, N.V. Solod, R.S. Zhyla // Functional Materials. — 2018. — Т. 25, № 1. — С. 151-157. — Бібліогр.: 14 назв. — англ. |
| collection | DSpace DC |
| container_title | Functional Materials |
| description | Peculiarities of thermal solid-phase transformations of Co₁₋xMnxHPO₄·1.5 H₂O (0 ≤ x ≤ 0.45), which accompanying the formation of a final product of thermolysis - anhydrous diphosphate solid solution with composition β-(Co₁₋xMnx)₂P₂O₇ (0 < x le; 0.45) are established. It is shown that low-temperature α-modification of the diphosphate is the first formed during heat treatment of the hydrogenphosphates Co₁₋xMnxHPO₄·1.5H₂O with 0 <x ≤ 0.15. Crystalline β-(Co₁₋xMnx)₂P₂O₇ (x≤0.15) is formed only after the polymorphic transformation of the α-form into the β-form. The formation of β-(Co₁₋xMnx)₂P₂O₇ with 0.15 < x ≤ 0.45 occurs bypassing the α-form. Free phosphoric acid during the heat treatment Co₁₋xMnxHPO₄·1.5H₂O (0 < x ≤ 0.45) are is not formed.
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| first_indexed | 2025-11-25T22:11:46Z |
| format | Article |
| fulltext | |
| id | nasplib_isofts_kiev_ua-123456789-154445 |
| institution | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| issn | 1027-5495 |
| language | English |
| last_indexed | 2025-11-25T22:11:46Z |
| publishDate | 2018 |
| publisher | НТК «Інститут монокристалів» НАН України |
| record_format | dspace |
| spelling | Antraptseva, N.M. Solod, N.V. Zhyla, R.S. 2019-06-15T15:42:09Z 2019-06-15T15:42:09Z 2018 Peculiarities of thermal solid-phase transformations of hydrogenphosphates Co(II)-Mn(II) / N.M. Antraptseva, N.V. Solod, R.S. Zhyla // Functional Materials. — 2018. — Т. 25, № 1. — С. 151-157. — Бібліогр.: 14 назв. — англ. 1027-5495 DOI:https://doi.org/10.15407/fm25.01.151 https://nasplib.isofts.kiev.ua/handle/123456789/154445 Peculiarities of thermal solid-phase transformations of Co₁₋xMnxHPO₄·1.5 H₂O (0 ≤ x ≤ 0.45), which accompanying the formation of a final product of thermolysis - anhydrous diphosphate solid solution with composition β-(Co₁₋xMnx)₂P₂O₇ (0 < x le; 0.45) are established. It is shown that low-temperature α-modification of the diphosphate is the first formed during heat treatment of the hydrogenphosphates Co₁₋xMnxHPO₄·1.5H₂O with 0 <x ≤ 0.15. Crystalline β-(Co₁₋xMnx)₂P₂O₇ (x≤0.15) is formed only after the polymorphic transformation of the α-form into the β-form. The formation of β-(Co₁₋xMnx)₂P₂O₇ with 0.15 < x ≤ 0.45 occurs bypassing the α-form. Free phosphoric acid during the heat treatment Co₁₋xMnxHPO₄·1.5H₂O (0 < x ≤ 0.45) are is not formed. en НТК «Інститут монокристалів» НАН України Functional Materials Technology Peculiarities of thermal solid-phase transformations of hydrogenphosphates Co(II)-Mn(II) Article published earlier |
| spellingShingle | Peculiarities of thermal solid-phase transformations of hydrogenphosphates Co(II)-Mn(II) Antraptseva, N.M. Solod, N.V. Zhyla, R.S. Technology |
| title | Peculiarities of thermal solid-phase transformations of hydrogenphosphates Co(II)-Mn(II) |
| title_full | Peculiarities of thermal solid-phase transformations of hydrogenphosphates Co(II)-Mn(II) |
| title_fullStr | Peculiarities of thermal solid-phase transformations of hydrogenphosphates Co(II)-Mn(II) |
| title_full_unstemmed | Peculiarities of thermal solid-phase transformations of hydrogenphosphates Co(II)-Mn(II) |
| title_short | Peculiarities of thermal solid-phase transformations of hydrogenphosphates Co(II)-Mn(II) |
| title_sort | peculiarities of thermal solid-phase transformations of hydrogenphosphates co(ii)-mn(ii) |
| topic | Technology |
| topic_facet | Technology |
| url | https://nasplib.isofts.kiev.ua/handle/123456789/154445 |
| work_keys_str_mv | AT antraptsevanm peculiaritiesofthermalsolidphasetransformationsofhydrogenphosphatescoiimnii AT solodnv peculiaritiesofthermalsolidphasetransformationsofhydrogenphosphatescoiimnii AT zhylars peculiaritiesofthermalsolidphasetransformationsofhydrogenphosphatescoiimnii |