Theoretical studies of the local structures and EPR parameters for Cu²⁺ center in Cd₂(NH₄)₂(SO₄)₃ single crystal

• Published in: Condensed Matter Physics
• Date: 2015
• Main Authors: Li, Ch.-Y., Chen, L.-B., Mao, J.-J., Zheng, X.-M.
• Format: Article
• Language: English
• Published: Інститут фізики конденсованих систем НАН України 2015
• Online Access: https://nasplib.isofts.kiev.ua/handle/123456789/155276
• Journal Title: Digital Library of Periodicals of National Academy of Sciences of Ukraine
• Cite this: Theoretical studies of the local structures and EPR parameters for Cu²⁺ center in Cd₂(NH₂)₂(SO₄)₃ single crystal / Ch.-Y. Li, L.-B. Chen, J.-J. Mao, X.-M. Zheng // Condensed Matter Physics. — 2015. — Т. 18, № 4. — С. 43701: 1–5. — Бібліогр.: 29 назв. — англ.

The electron paramagnetic resonance (EPR) parameters (g factors gi and the hyperfine structure constants Ai, i = x, y, z) are interpreted by using the perturbation formulae for a 3d⁹ ion in rhombically (D₂h) elongated octahedra. In the calculated formulae, the crystal field parameters are set up fro...