Effect of iodine impurity on the absorption spectrum and phase transitions in CsPbCl₃ thin films

The absorption spectra of thin films of solid solutions CsPb(Cl₁₋xIx)₃ 0≤x≤1 were studied. It has been found that at low concentrations x≤0.2, excitonic spectra of a amalgamation type (according to the classification of Onodera-Tojazawa) are formed. The concentration shift of the exciton bands with...

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Veröffentlicht in:Functional Materials
Datum:2018
Hauptverfasser: Kovalenko, E.N., Yunakova, O.N., Yunakov, N.N.
Format: Artikel
Sprache:English
Veröffentlicht: НТК «Інститут монокристалів» НАН України 2018
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Online Zugang:https://nasplib.isofts.kiev.ua/handle/123456789/157134
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Zitieren:Effect of iodine impurity on the absorption spectrum and phase transitions in CsPbCl₃ thin films / E.N. Kovalenko, O.N. Yunakova, N.N. Yunakov // Functional Materials. — 2018. — Т. 25, № 2. — С. 218-224. — Бібліогр.: 24 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
id nasplib_isofts_kiev_ua-123456789-157134
record_format dspace
spelling Kovalenko, E.N.
Yunakova, O.N.
Yunakov, N.N.
2019-06-19T16:18:04Z
2019-06-19T16:18:04Z
2018
Effect of iodine impurity on the absorption spectrum and phase transitions in CsPbCl₃ thin films / E.N. Kovalenko, O.N. Yunakova, N.N. Yunakov // Functional Materials. — 2018. — Т. 25, № 2. — С. 218-224. — Бібліогр.: 24 назв. — англ.
1027-5495
DOI:https://doi.org/10.15407/fm25.02.218
https://nasplib.isofts.kiev.ua/handle/123456789/157134
The absorption spectra of thin films of solid solutions CsPb(Cl₁₋xIx)₃ 0≤x≤1 were studied. It has been found that at low concentrations x≤0.2, excitonic spectra of a amalgamation type (according to the classification of Onodera-Tojazawa) are formed. The concentration shift of the exciton bands with increasing x at x = 0.3 indicates the formation of the exciton spectrum of a persistence type in the interval 0.3≤x < 1. The iodine impurity leads to an insignificant increase of the phase ransition temperatures in the orthorhombic (Tc₃) and cubic (Tc₁) phases of CsPbCl₃.
en
НТК «Інститут монокристалів» НАН України
Functional Materials
Characterization and properties
Effect of iodine impurity on the absorption spectrum and phase transitions in CsPbCl₃ thin films
Article
published earlier
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
title Effect of iodine impurity on the absorption spectrum and phase transitions in CsPbCl₃ thin films
spellingShingle Effect of iodine impurity on the absorption spectrum and phase transitions in CsPbCl₃ thin films
Kovalenko, E.N.
Yunakova, O.N.
Yunakov, N.N.
Characterization and properties
title_short Effect of iodine impurity on the absorption spectrum and phase transitions in CsPbCl₃ thin films
title_full Effect of iodine impurity on the absorption spectrum and phase transitions in CsPbCl₃ thin films
title_fullStr Effect of iodine impurity on the absorption spectrum and phase transitions in CsPbCl₃ thin films
title_full_unstemmed Effect of iodine impurity on the absorption spectrum and phase transitions in CsPbCl₃ thin films
title_sort effect of iodine impurity on the absorption spectrum and phase transitions in cspbcl₃ thin films
author Kovalenko, E.N.
Yunakova, O.N.
Yunakov, N.N.
author_facet Kovalenko, E.N.
Yunakova, O.N.
Yunakov, N.N.
topic Characterization and properties
topic_facet Characterization and properties
publishDate 2018
language English
container_title Functional Materials
publisher НТК «Інститут монокристалів» НАН України
format Article
description The absorption spectra of thin films of solid solutions CsPb(Cl₁₋xIx)₃ 0≤x≤1 were studied. It has been found that at low concentrations x≤0.2, excitonic spectra of a amalgamation type (according to the classification of Onodera-Tojazawa) are formed. The concentration shift of the exciton bands with increasing x at x = 0.3 indicates the formation of the exciton spectrum of a persistence type in the interval 0.3≤x < 1. The iodine impurity leads to an insignificant increase of the phase ransition temperatures in the orthorhombic (Tc₃) and cubic (Tc₁) phases of CsPbCl₃.
issn 1027-5495
url https://nasplib.isofts.kiev.ua/handle/123456789/157134
citation_txt Effect of iodine impurity on the absorption spectrum and phase transitions in CsPbCl₃ thin films / E.N. Kovalenko, O.N. Yunakova, N.N. Yunakov // Functional Materials. — 2018. — Т. 25, № 2. — С. 218-224. — Бібліогр.: 24 назв. — англ.
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