Effect of iodine impurity on the absorption spectrum and phase transitions in CsPbCl₃ thin films

The absorption spectra of thin films of solid solutions CsPb(Cl₁₋xIx)₃ 0≤x≤1 were studied. It has been found that at low concentrations x≤0.2, excitonic spectra of a amalgamation type (according to the classification of Onodera-Tojazawa) are formed. The concentration shift of the exciton bands with...

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Опубліковано в: :Functional Materials
Дата:2018
Автори: Kovalenko, E.N., Yunakova, O.N., Yunakov, N.N.
Формат: Стаття
Мова:Англійська
Опубліковано: НТК «Інститут монокристалів» НАН України 2018
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Онлайн доступ:https://nasplib.isofts.kiev.ua/handle/123456789/157134
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Effect of iodine impurity on the absorption spectrum and phase transitions in CsPbCl₃ thin films / E.N. Kovalenko, O.N. Yunakova, N.N. Yunakov // Functional Materials. — 2018. — Т. 25, № 2. — С. 218-224. — Бібліогр.: 24 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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author Kovalenko, E.N.
Yunakova, O.N.
Yunakov, N.N.
author_facet Kovalenko, E.N.
Yunakova, O.N.
Yunakov, N.N.
citation_txt Effect of iodine impurity on the absorption spectrum and phase transitions in CsPbCl₃ thin films / E.N. Kovalenko, O.N. Yunakova, N.N. Yunakov // Functional Materials. — 2018. — Т. 25, № 2. — С. 218-224. — Бібліогр.: 24 назв. — англ.
collection DSpace DC
container_title Functional Materials
description The absorption spectra of thin films of solid solutions CsPb(Cl₁₋xIx)₃ 0≤x≤1 were studied. It has been found that at low concentrations x≤0.2, excitonic spectra of a amalgamation type (according to the classification of Onodera-Tojazawa) are formed. The concentration shift of the exciton bands with increasing x at x = 0.3 indicates the formation of the exciton spectrum of a persistence type in the interval 0.3≤x < 1. The iodine impurity leads to an insignificant increase of the phase ransition temperatures in the orthorhombic (Tc₃) and cubic (Tc₁) phases of CsPbCl₃.
first_indexed 2025-12-07T19:16:07Z
format Article
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institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
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language English
last_indexed 2025-12-07T19:16:07Z
publishDate 2018
publisher НТК «Інститут монокристалів» НАН України
record_format dspace
spelling Kovalenko, E.N.
Yunakova, O.N.
Yunakov, N.N.
2019-06-19T16:18:04Z
2019-06-19T16:18:04Z
2018
Effect of iodine impurity on the absorption spectrum and phase transitions in CsPbCl₃ thin films / E.N. Kovalenko, O.N. Yunakova, N.N. Yunakov // Functional Materials. — 2018. — Т. 25, № 2. — С. 218-224. — Бібліогр.: 24 назв. — англ.
1027-5495
DOI:https://doi.org/10.15407/fm25.02.218
https://nasplib.isofts.kiev.ua/handle/123456789/157134
The absorption spectra of thin films of solid solutions CsPb(Cl₁₋xIx)₃ 0≤x≤1 were studied. It has been found that at low concentrations x≤0.2, excitonic spectra of a amalgamation type (according to the classification of Onodera-Tojazawa) are formed. The concentration shift of the exciton bands with increasing x at x = 0.3 indicates the formation of the exciton spectrum of a persistence type in the interval 0.3≤x < 1. The iodine impurity leads to an insignificant increase of the phase ransition temperatures in the orthorhombic (Tc₃) and cubic (Tc₁) phases of CsPbCl₃.
en
НТК «Інститут монокристалів» НАН України
Functional Materials
Characterization and properties
Effect of iodine impurity on the absorption spectrum and phase transitions in CsPbCl₃ thin films
Article
published earlier
spellingShingle Effect of iodine impurity on the absorption spectrum and phase transitions in CsPbCl₃ thin films
Kovalenko, E.N.
Yunakova, O.N.
Yunakov, N.N.
Characterization and properties
title Effect of iodine impurity on the absorption spectrum and phase transitions in CsPbCl₃ thin films
title_full Effect of iodine impurity on the absorption spectrum and phase transitions in CsPbCl₃ thin films
title_fullStr Effect of iodine impurity on the absorption spectrum and phase transitions in CsPbCl₃ thin films
title_full_unstemmed Effect of iodine impurity on the absorption spectrum and phase transitions in CsPbCl₃ thin films
title_short Effect of iodine impurity on the absorption spectrum and phase transitions in CsPbCl₃ thin films
title_sort effect of iodine impurity on the absorption spectrum and phase transitions in cspbcl₃ thin films
topic Characterization and properties
topic_facet Characterization and properties
url https://nasplib.isofts.kiev.ua/handle/123456789/157134
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