Boron removal from metallurgical grade silicon and Si-Sn alloy through slag refining with gas blowing

A combined method of slag refining and gas blowing technique were used for boron removal from metallurgical grade silicon and 75%wt Si-Sn alloy using the 45%CaO-45%SiO₂-10%CaCl₂ slag with the use of Ar gas and Ar-20%O₂ mixed gas. Increasing gas flow rate from 50 to 250 ml/min shows enhancement in B...

Full description

Saved in:
Bibliographic Details
Published in:Functional Materials
Date:2018
Main Authors: Rowaid Al-khazraji, Yaqiong Li, Lifeng Zhang
Format: Article
Language:English
Published: НТК «Інститут монокристалів» НАН України 2018
Subjects:
Online Access:https://nasplib.isofts.kiev.ua/handle/123456789/157193
Tags: Add Tag
No Tags, Be the first to tag this record!
Journal Title:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Cite this:Boron removal from metallurgical grade silicon and Si-Sn alloy through slag refining with gas blowing / Rowaid Al-khazraji, Yaqiong Li, Lifeng Zhang // Functional Materials. — 2018. — Т. 25, № 3. — С. 625-631. — Бібліогр.: 21 назв. — англ.

Institution

Digital Library of Periodicals of National Academy of Sciences of Ukraine
_version_ 1862617777042358272
author Rowaid Al-khazraji
Yaqiong Li
Lifeng Zhang
author_facet Rowaid Al-khazraji
Yaqiong Li
Lifeng Zhang
citation_txt Boron removal from metallurgical grade silicon and Si-Sn alloy through slag refining with gas blowing / Rowaid Al-khazraji, Yaqiong Li, Lifeng Zhang // Functional Materials. — 2018. — Т. 25, № 3. — С. 625-631. — Бібліогр.: 21 назв. — англ.
collection DSpace DC
container_title Functional Materials
description A combined method of slag refining and gas blowing technique were used for boron removal from metallurgical grade silicon and 75%wt Si-Sn alloy using the 45%CaO-45%SiO₂-10%CaCl₂ slag with the use of Ar gas and Ar-20%O₂ mixed gas. Increasing gas flow rate from 50 to 250 ml/min shows enhancement in B removal. At fixed conditions the Ar-20%O₂ mixed gas blowing shows a good removal efficiency of boron about 85% and 96% to MG and Si-Sn alloy respectively, compared with the single Ar gas blowing with 78.6% and 88% to MG and Si-Sn alloy respectively. Changes in slag composition representing by decreasing in all compounds especially CaCl₂ attached with increase in Al₂O₃. The B impurities after the treatment found with low intensity in Si matrix but with high intensity in slag phase and Sn phase. Boron removal controlled by mass transfer in slag phase with mass transfer coefficients of 3.38ċ10⁻⁴cm.s⁻¹ and 7.2ċ10⁻⁵cm.s⁻¹ in Si and Si-Sn alloy respectively.
first_indexed 2025-12-07T13:12:56Z
format Article
fulltext
id nasplib_isofts_kiev_ua-123456789-157193
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
issn 1027-5495
language English
last_indexed 2025-12-07T13:12:56Z
publishDate 2018
publisher НТК «Інститут монокристалів» НАН України
record_format dspace
spelling Rowaid Al-khazraji
Yaqiong Li
Lifeng Zhang
2019-06-19T17:15:53Z
2019-06-19T17:15:53Z
2018
Boron removal from metallurgical grade silicon and Si-Sn alloy through slag refining with gas blowing / Rowaid Al-khazraji, Yaqiong Li, Lifeng Zhang // Functional Materials. — 2018. — Т. 25, № 3. — С. 625-631. — Бібліогр.: 21 назв. — англ.
1027-5495
DOI:https://doi.org/10.15407/fm25.03.625
https://nasplib.isofts.kiev.ua/handle/123456789/157193
A combined method of slag refining and gas blowing technique were used for boron removal from metallurgical grade silicon and 75%wt Si-Sn alloy using the 45%CaO-45%SiO₂-10%CaCl₂ slag with the use of Ar gas and Ar-20%O₂ mixed gas. Increasing gas flow rate from 50 to 250 ml/min shows enhancement in B removal. At fixed conditions the Ar-20%O₂ mixed gas blowing shows a good removal efficiency of boron about 85% and 96% to MG and Si-Sn alloy respectively, compared with the single Ar gas blowing with 78.6% and 88% to MG and Si-Sn alloy respectively. Changes in slag composition representing by decreasing in all compounds especially CaCl₂ attached with increase in Al₂O₃. The B impurities after the treatment found with low intensity in Si matrix but with high intensity in slag phase and Sn phase. Boron removal controlled by mass transfer in slag phase with mass transfer coefficients of 3.38ċ10⁻⁴cm.s⁻¹ and 7.2ċ10⁻⁵cm.s⁻¹ in Si and Si-Sn alloy respectively.
en
НТК «Інститут монокристалів» НАН України
Functional Materials
Technology
Boron removal from metallurgical grade silicon and Si-Sn alloy through slag refining with gas blowing
Article
published earlier
spellingShingle Boron removal from metallurgical grade silicon and Si-Sn alloy through slag refining with gas blowing
Rowaid Al-khazraji
Yaqiong Li
Lifeng Zhang
Technology
title Boron removal from metallurgical grade silicon and Si-Sn alloy through slag refining with gas blowing
title_full Boron removal from metallurgical grade silicon and Si-Sn alloy through slag refining with gas blowing
title_fullStr Boron removal from metallurgical grade silicon and Si-Sn alloy through slag refining with gas blowing
title_full_unstemmed Boron removal from metallurgical grade silicon and Si-Sn alloy through slag refining with gas blowing
title_short Boron removal from metallurgical grade silicon and Si-Sn alloy through slag refining with gas blowing
title_sort boron removal from metallurgical grade silicon and si-sn alloy through slag refining with gas blowing
topic Technology
topic_facet Technology
url https://nasplib.isofts.kiev.ua/handle/123456789/157193
work_keys_str_mv AT rowaidalkhazraji boronremovalfrommetallurgicalgradesiliconandsisnalloythroughslagrefiningwithgasblowing
AT yaqiongli boronremovalfrommetallurgicalgradesiliconandsisnalloythroughslagrefiningwithgasblowing
AT lifengzhang boronremovalfrommetallurgicalgradesiliconandsisnalloythroughslagrefiningwithgasblowing