Temperature and concentration dependences of specific heat of Bi₁-xSbx solid solutions

For Bi₁-xSbx solid solutions, the concentration (x = 0 - 0.12) and temperature (170-525 K) dependences of specific heat Cp were obtained. At all temperatures studied, three peaks of Cp were observed near x = 0.015, x = 0.037, and x = 0.07. The observed effects were attributed to critical phenomena a...

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Veröffentlicht in:Functional Materials
Datum:2018
Hauptverfasser: Rogacheva, E.I., Doroshenko, A.N., Nashchekina, O.N.
Format: Artikel
Sprache:Englisch
Veröffentlicht: НТК «Інститут монокристалів» НАН України 2018
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Online Zugang:https://nasplib.isofts.kiev.ua/handle/123456789/157424
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Zitieren:Temperature and concentration dependences of specific heat of Bi₁-xSbx solid solutions / E.I. Rogacheva, A.N. Doroshenko, O.N. Nashchekina // Functional Materials. — 2018. — Т. 25, № 4. — С. 720-728. — Бібліогр.: 42 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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author Rogacheva, E.I.
Doroshenko, A.N.
Nashchekina, O.N.
author_facet Rogacheva, E.I.
Doroshenko, A.N.
Nashchekina, O.N.
citation_txt Temperature and concentration dependences of specific heat of Bi₁-xSbx solid solutions / E.I. Rogacheva, A.N. Doroshenko, O.N. Nashchekina // Functional Materials. — 2018. — Т. 25, № 4. — С. 720-728. — Бібліогр.: 42 назв. — англ.
collection DSpace DC
container_title Functional Materials
description For Bi₁-xSbx solid solutions, the concentration (x = 0 - 0.12) and temperature (170-525 K) dependences of specific heat Cp were obtained. At all temperatures studied, three peaks of Cp were observed near x = 0.015, x = 0.037, and x = 0.07. The observed effects were attributed to critical phenomena accompanying the second-order phase transitions: percolation transition from dilute to concentrated solid solutions, the transition to a gapless state, and the semimetal-semiconductor transition, respectively. It was shown that the values of critical indexes (α = 0.11±0.01) are the same not only for different peaks but also for different temperatures and correspond to the values theoretically calculated within the framework of scale-invariant theory for three-dimensional (3D) models.
first_indexed 2025-12-07T16:10:58Z
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institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
issn 1027-5495
language English
last_indexed 2025-12-07T16:10:58Z
publishDate 2018
publisher НТК «Інститут монокристалів» НАН України
record_format dspace
spelling Rogacheva, E.I.
Doroshenko, A.N.
Nashchekina, O.N.
2019-06-20T03:26:40Z
2019-06-20T03:26:40Z
2018
Temperature and concentration dependences of specific heat of Bi₁-xSbx solid solutions / E.I. Rogacheva, A.N. Doroshenko, O.N. Nashchekina // Functional Materials. — 2018. — Т. 25, № 4. — С. 720-728. — Бібліогр.: 42 назв. — англ.
1027-5495
DOI:https://doi.org/10.15407/fm25.04.720
https://nasplib.isofts.kiev.ua/handle/123456789/157424
For Bi₁-xSbx solid solutions, the concentration (x = 0 - 0.12) and temperature (170-525 K) dependences of specific heat Cp were obtained. At all temperatures studied, three peaks of Cp were observed near x = 0.015, x = 0.037, and x = 0.07. The observed effects were attributed to critical phenomena accompanying the second-order phase transitions: percolation transition from dilute to concentrated solid solutions, the transition to a gapless state, and the semimetal-semiconductor transition, respectively. It was shown that the values of critical indexes (α = 0.11±0.01) are the same not only for different peaks but also for different temperatures and correspond to the values theoretically calculated within the framework of scale-invariant theory for three-dimensional (3D) models.
en
НТК «Інститут монокристалів» НАН України
Functional Materials
Characterization and properties
Temperature and concentration dependences of specific heat of Bi₁-xSbx solid solutions
Article
published earlier
spellingShingle Temperature and concentration dependences of specific heat of Bi₁-xSbx solid solutions
Rogacheva, E.I.
Doroshenko, A.N.
Nashchekina, O.N.
Characterization and properties
title Temperature and concentration dependences of specific heat of Bi₁-xSbx solid solutions
title_full Temperature and concentration dependences of specific heat of Bi₁-xSbx solid solutions
title_fullStr Temperature and concentration dependences of specific heat of Bi₁-xSbx solid solutions
title_full_unstemmed Temperature and concentration dependences of specific heat of Bi₁-xSbx solid solutions
title_short Temperature and concentration dependences of specific heat of Bi₁-xSbx solid solutions
title_sort temperature and concentration dependences of specific heat of bi₁-xsbx solid solutions
topic Characterization and properties
topic_facet Characterization and properties
url https://nasplib.isofts.kiev.ua/handle/123456789/157424
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AT doroshenkoan temperatureandconcentrationdependencesofspecificheatofbi1xsbxsolidsolutions
AT nashchekinaon temperatureandconcentrationdependencesofspecificheatofbi1xsbxsolidsolutions