The chemical, phase composition and optical properties of ZnxCd₁-xS films obtained by close spaced vacuum sublimation
The optical properties, chemical and phase composition of ZnxCd₁-xS films obtained by close-spaced vacuum sublimation (CSS) were studied using X-ray diffraction, energy dispersive X-ray analysis and optical spectroscopy methods. The solid solution films were deposited at the substrate and evaporator...
Gespeichert in:
| Veröffentlicht in: | Functional Materials |
|---|---|
| Datum: | 2019 |
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | English |
| Veröffentlicht: |
НТК «Інститут монокристалів» НАН України
2019
|
| Schlagworte: | |
| Online Zugang: | https://nasplib.isofts.kiev.ua/handle/123456789/157442 |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Zitieren: | The chemical, phase composition and optical properties of ZnxCd₁-xS films obtained by close spaced vacuum sublimation / Yu. Yeromenko, A. Opanasyuk, A. Voznyi, I. Shpetnyi, Yu. Gnatenko, V. Grebinaha // Functional Materials. — 2019. — Т. 26, № 1. — С. 16-22. — Бібліогр.: 30 назв. — англ. |
Institution
Digital Library of Periodicals of National Academy of Sciences of Ukraine| id |
nasplib_isofts_kiev_ua-123456789-157442 |
|---|---|
| record_format |
dspace |
| spelling |
Yeromenko, Yu. Opanasyuk, A. Voznyi, A. Shpetnyi, I. Gnatenko, Yu. Grebinaha, V. 2019-06-20T03:29:17Z 2019-06-20T03:29:17Z 2019 The chemical, phase composition and optical properties of ZnxCd₁-xS films obtained by close spaced vacuum sublimation / Yu. Yeromenko, A. Opanasyuk, A. Voznyi, I. Shpetnyi, Yu. Gnatenko, V. Grebinaha // Functional Materials. — 2019. — Т. 26, № 1. — С. 16-22. — Бібліогр.: 30 назв. — англ. 1027-5495 DOI:https://doi.org/10.15407/fm26.01.16 https://nasplib.isofts.kiev.ua/handle/123456789/157442 The optical properties, chemical and phase composition of ZnxCd₁-xS films obtained by close-spaced vacuum sublimation (CSS) were studied using X-ray diffraction, energy dispersive X-ray analysis and optical spectroscopy methods. The solid solution films were deposited at the substrate and evaporator temperatures of Ts = 573 K and Te = 1273 K, respectively. ZnS and CdS powders were mixed with different weight ratios (x = 0; 0.2; 0.4; 0.6; 0.8; 1.0) for further deposition of ZnxCd₁-xS films. It was found that the optical properties (band gap, transmission and absorption coefficients) of ZnxCd₁-xS films depends on the chemical composition and can be controlled by the weight percentages of the initial powders. It was found that the actual zinc concentrations in the films is higher than expected and the film thickness reduces with increasing of x. This results demonstrate that ZnxCd₁-xS solid solutions films obtained by CSS have improved optical parameters, high crystal quality and good stoichiometry. en НТК «Інститут монокристалів» НАН України Functional Materials Characterization and properties The chemical, phase composition and optical properties of ZnxCd₁-xS films obtained by close spaced vacuum sublimation Article published earlier |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| title |
The chemical, phase composition and optical properties of ZnxCd₁-xS films obtained by close spaced vacuum sublimation |
| spellingShingle |
The chemical, phase composition and optical properties of ZnxCd₁-xS films obtained by close spaced vacuum sublimation Yeromenko, Yu. Opanasyuk, A. Voznyi, A. Shpetnyi, I. Gnatenko, Yu. Grebinaha, V. Characterization and properties |
| title_short |
The chemical, phase composition and optical properties of ZnxCd₁-xS films obtained by close spaced vacuum sublimation |
| title_full |
The chemical, phase composition and optical properties of ZnxCd₁-xS films obtained by close spaced vacuum sublimation |
| title_fullStr |
The chemical, phase composition and optical properties of ZnxCd₁-xS films obtained by close spaced vacuum sublimation |
| title_full_unstemmed |
The chemical, phase composition and optical properties of ZnxCd₁-xS films obtained by close spaced vacuum sublimation |
| title_sort |
chemical, phase composition and optical properties of znxcd₁-xs films obtained by close spaced vacuum sublimation |
| author |
Yeromenko, Yu. Opanasyuk, A. Voznyi, A. Shpetnyi, I. Gnatenko, Yu. Grebinaha, V. |
| author_facet |
Yeromenko, Yu. Opanasyuk, A. Voznyi, A. Shpetnyi, I. Gnatenko, Yu. Grebinaha, V. |
| topic |
Characterization and properties |
| topic_facet |
Characterization and properties |
| publishDate |
2019 |
| language |
English |
| container_title |
Functional Materials |
| publisher |
НТК «Інститут монокристалів» НАН України |
| format |
Article |
| description |
The optical properties, chemical and phase composition of ZnxCd₁-xS films obtained by close-spaced vacuum sublimation (CSS) were studied using X-ray diffraction, energy dispersive X-ray analysis and optical spectroscopy methods. The solid solution films were deposited at the substrate and evaporator temperatures of Ts = 573 K and Te = 1273 K, respectively. ZnS and CdS powders were mixed with different weight ratios (x = 0; 0.2; 0.4; 0.6; 0.8; 1.0) for further deposition of ZnxCd₁-xS films. It was found that the optical properties (band gap, transmission and absorption coefficients) of ZnxCd₁-xS films depends on the chemical composition and can be controlled by the weight percentages of the initial powders. It was found that the actual zinc concentrations in the films is higher than expected and the film thickness reduces with increasing of x. This results demonstrate that ZnxCd₁-xS solid solutions films obtained by CSS have improved optical parameters, high crystal quality and good stoichiometry.
|
| issn |
1027-5495 |
| url |
https://nasplib.isofts.kiev.ua/handle/123456789/157442 |
| citation_txt |
The chemical, phase composition and optical properties of ZnxCd₁-xS films obtained by close spaced vacuum sublimation / Yu. Yeromenko, A. Opanasyuk, A. Voznyi, I. Shpetnyi, Yu. Gnatenko, V. Grebinaha // Functional Materials. — 2019. — Т. 26, № 1. — С. 16-22. — Бібліогр.: 30 назв. — англ. |
| work_keys_str_mv |
AT yeromenkoyu thechemicalphasecompositionandopticalpropertiesofznxcd1xsfilmsobtainedbyclosespacedvacuumsublimation AT opanasyuka thechemicalphasecompositionandopticalpropertiesofznxcd1xsfilmsobtainedbyclosespacedvacuumsublimation AT voznyia thechemicalphasecompositionandopticalpropertiesofznxcd1xsfilmsobtainedbyclosespacedvacuumsublimation AT shpetnyii thechemicalphasecompositionandopticalpropertiesofznxcd1xsfilmsobtainedbyclosespacedvacuumsublimation AT gnatenkoyu thechemicalphasecompositionandopticalpropertiesofznxcd1xsfilmsobtainedbyclosespacedvacuumsublimation AT grebinahav thechemicalphasecompositionandopticalpropertiesofznxcd1xsfilmsobtainedbyclosespacedvacuumsublimation AT yeromenkoyu chemicalphasecompositionandopticalpropertiesofznxcd1xsfilmsobtainedbyclosespacedvacuumsublimation AT opanasyuka chemicalphasecompositionandopticalpropertiesofznxcd1xsfilmsobtainedbyclosespacedvacuumsublimation AT voznyia chemicalphasecompositionandopticalpropertiesofznxcd1xsfilmsobtainedbyclosespacedvacuumsublimation AT shpetnyii chemicalphasecompositionandopticalpropertiesofznxcd1xsfilmsobtainedbyclosespacedvacuumsublimation AT gnatenkoyu chemicalphasecompositionandopticalpropertiesofznxcd1xsfilmsobtainedbyclosespacedvacuumsublimation AT grebinahav chemicalphasecompositionandopticalpropertiesofznxcd1xsfilmsobtainedbyclosespacedvacuumsublimation |
| first_indexed |
2025-12-07T16:42:25Z |
| last_indexed |
2025-12-07T16:42:25Z |
| _version_ |
1850868493644201984 |