Facile and scalable synthesis of Ti₅Si₃ nanoparticles via solid-state route in an autoclave

• Published in: Сверхтвердые материалы
• Date: 2017
• Main Authors: Mao, W., Bao, K., Cao, F., Ye, L., Xie, H., Li, B., Wang, W.
• Format: Article
• Language: English
• Published: Інститут надтвердих матеріалів ім. В.М. Бакуля НАН України 2017
• Subjects: Получение, структура, свойства
• Online Access: https://nasplib.isofts.kiev.ua/handle/123456789/160107
• Journal Title: Digital Library of Periodicals of National Academy of Sciences of Ukraine
• Cite this: Facile and scalable synthesis of Ti₅Si₃ nanoparticles via solid-state route in an autoclave / W. Mao, K. Bao, F. Cao, L. Ye, H. Xie, B. Li, W. Wang // Сверхтвердые материалы. — 2017. — № 2. — С. 56-61. — Бібліогр.: 21 назв. — англ.

A novel method of the synthesis of titanium silicide nanoparticles via solid-state route in an autoclave at 700 °C is reported. The reaction of titanium silicide could be described briefly as: 5TiO₂ + 3Si + 20Li = Ti₅Si₃ + 10Li₂O. XRD pattern indicated that the product was hexagonal Ti₅Si₃. The Ti₅S...