Новий тип координації карбациламідофосфатного ліганду: будова та властивості комплексу срібла (I) з диметил-N-трихлороацетиламідофосфатом
A new coordination compound of silver (I) with dimethyl-N-trichloroacetylamidophosphate [L]– has been obtained. Based on IR data, the N-coordination mode of the carbacylamidophosphate ligand is suggested. The crystal structure of Na[AgL2]·CH3CN has been determined. The complex crystallizes in the tr...
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| Date: | 2007 |
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| Main Authors: | , , |
| Format: | Article |
| Language: | Ukrainian |
| Published: |
Видавничий дім "Академперіодика" НАН України
2007
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| Subjects: | |
| Online Access: | https://nasplib.isofts.kiev.ua/handle/123456789/1728 |
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| Journal Title: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Cite this: | Новий тип координації карбациламідофосфатного ліганду: будова та властивості комплексу срібла (I) з диметил-N-трихлороацетиламідофосфатом / В.О. Труш, К.В. Домасевич, В.М. Амірханов // Доп. НАН України. — 2007. — N 7. — С. 147–152. — Бібліогр.: 15 назв. — укp. |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine| Summary: | A new coordination compound of silver (I) with dimethyl-N-trichloroacetylamidophosphate [L]– has been obtained. Based on IR data, the N-coordination mode of the carbacylamidophosphate ligand is suggested. The crystal structure of Na[AgL2]·CH3CN has been determined. The complex crystallizes in the trigonal system: b = 20.353(3) nm, c = 30.514(6) nm, Z = 18; space group R3c. The substance has ionic structure, the ligands are coordinated in the monodentate form via the nitrogen atoms with the formation of the complex anion [AgL2]–: the silver atom has a coordination number (CN) equal to 2, the angle N–Ag=N´ is 163.4(3)°. The sodium ion contacts with the oxygen atoms of C(O) and P(O) groups forming the six-membered chelate metallocycles: CN = 6.
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| ISSN: | 1025-6415 |