Luminescence and ODMR studies of X-traps for triplet excitons in organic crystals
The excited triplet states of shallow X-traps in neat single crystals of 4,4-dichlorobenzophenone were studied at liquid helium temperature by luminescence spectroscopy and magnetic resonance with optical detection. The vibrational phosphorescence bands, the polarization of phosphorescence spectra,...
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| Опубліковано в: : | Физика низких температур |
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| Дата: | 1997 |
| Автори: | , , , , , , , |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
1997
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| Онлайн доступ: | https://nasplib.isofts.kiev.ua/handle/123456789/175038 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Luminescence and ODMR studies of X-traps for triplet excitons in organic crystals / A.А. Avdeenko, L.М. Buravtseva, V.S. Gorobchenko, V.V. Eremenko, S.V. lzvekov, А.Е. Кravchenko, О.S. Pyshkin, and V.І. Sugakov // Физика низких температур. — 1997. — Т. 23, № 3. — С. 334-337. — Бібліогр.: 20 назв. — англ. |
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Avdeenko, A.A. Buravtseva, L.M. Gorobchenko, V.S. Eremenko, V.V. Izvekov, S.V. Kravchenko, A.E. Pyshkin, O.S. Sugakov, V.I. 2021-01-30T08:52:13Z 2021-01-30T08:52:13Z 1997 Luminescence and ODMR studies of X-traps for triplet excitons in organic crystals / A.А. Avdeenko, L.М. Buravtseva, V.S. Gorobchenko, V.V. Eremenko, S.V. lzvekov, А.Е. Кravchenko, О.S. Pyshkin, and V.І. Sugakov // Физика низких температур. — 1997. — Т. 23, № 3. — С. 334-337. — Бібліогр.: 20 назв. — англ. 0132-6414 PACS: 71.55.Ht, 76.70.Hb, 78.55.Kz https://nasplib.isofts.kiev.ua/handle/123456789/175038 The excited triplet states of shallow X-traps in neat single crystals of 4,4-dichlorobenzophenone were studied at liquid helium temperature by luminescence spectroscopy and magnetic resonance with optical detection. The vibrational phosphorescence bands, the polarization of phosphorescence spectra, and the triplet zero-field splitting parameters of these traps have been analyzed. A specific model of the structure defect (a molecule is turned by 180° on its long axis) has been considered in organic crystals of benzophenone type which consist of molecules whose dipole moments compensate each other in a unit cell. The calculated depth of such a dipole X-trap for triplet excitons in 4,4-dichlorobenzophenone crystals at the account of a defect molecule relaxation upon its slewing was found to be comparable with the experimental one. The research described in this publication was made possible, in part, bу Grants U9JOOO and U9J200 from the International Science Foundation and Grant ISSEP SPU 04265 from the Soros Science Education Program of the International Renaissance Foundation. en Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України Физика низких температур Luminescence and ODMR studies of X-traps for triplet excitons in organic crystals Article published earlier |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| title |
Luminescence and ODMR studies of X-traps for triplet excitons in organic crystals |
| spellingShingle |
Luminescence and ODMR studies of X-traps for triplet excitons in organic crystals Avdeenko, A.A. Buravtseva, L.M. Gorobchenko, V.S. Eremenko, V.V. Izvekov, S.V. Kravchenko, A.E. Pyshkin, O.S. Sugakov, V.I. |
| title_short |
Luminescence and ODMR studies of X-traps for triplet excitons in organic crystals |
| title_full |
Luminescence and ODMR studies of X-traps for triplet excitons in organic crystals |
| title_fullStr |
Luminescence and ODMR studies of X-traps for triplet excitons in organic crystals |
| title_full_unstemmed |
Luminescence and ODMR studies of X-traps for triplet excitons in organic crystals |
| title_sort |
luminescence and odmr studies of x-traps for triplet excitons in organic crystals |
| author |
Avdeenko, A.A. Buravtseva, L.M. Gorobchenko, V.S. Eremenko, V.V. Izvekov, S.V. Kravchenko, A.E. Pyshkin, O.S. Sugakov, V.I. |
| author_facet |
Avdeenko, A.A. Buravtseva, L.M. Gorobchenko, V.S. Eremenko, V.V. Izvekov, S.V. Kravchenko, A.E. Pyshkin, O.S. Sugakov, V.I. |
| publishDate |
1997 |
| language |
English |
| container_title |
Физика низких температур |
| publisher |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| format |
Article |
| description |
The excited triplet states of shallow X-traps in neat single crystals of 4,4-dichlorobenzophenone were studied at liquid helium temperature by luminescence spectroscopy and magnetic resonance with optical detection. The vibrational phosphorescence bands, the polarization of phosphorescence spectra, and the triplet zero-field splitting parameters of these traps have been analyzed. A specific model of the structure defect (a molecule is turned by 180° on its long axis) has been considered in organic crystals of benzophenone type which consist of molecules whose dipole moments compensate each other in a unit cell. The calculated depth of such a dipole X-trap for triplet excitons in 4,4-dichlorobenzophenone crystals at the account of a defect molecule relaxation upon its slewing was found to be comparable with the experimental one.
|
| issn |
0132-6414 |
| url |
https://nasplib.isofts.kiev.ua/handle/123456789/175038 |
| citation_txt |
Luminescence and ODMR studies of X-traps for triplet excitons in organic crystals / A.А. Avdeenko, L.М. Buravtseva, V.S. Gorobchenko, V.V. Eremenko, S.V. lzvekov, А.Е. Кravchenko, О.S. Pyshkin, and V.І. Sugakov // Физика низких температур. — 1997. — Т. 23, № 3. — С. 334-337. — Бібліогр.: 20 назв. — англ. |
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2025-12-07T20:07:46Z |
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2025-12-07T20:07:46Z |
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