Thermal expansion of organic superconductor κ-(D₄-BEDT-TTF)₂Cu{N(CN)₂}Br. Isotopic effect

Linear thermal expansion coefficient (LTEC) of single crystal κ-(D₄-BEDT-TTF)₂Cu[N(CN)₂]Br was studied across the crystal layers in the temperature range 2–290 K using the method of precise capacitive dilatometry. Below Tc = 11.6 K the LTEC of the sample had a small negative value, which is apparent...

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Published in:Физика низких температур
Date:2017
Main Authors: Dolbin, A.V., Khlistuck, M.V., Eselson, V.B., Gavrilko, V.G., Vinnikov, N.A., Basnukaeva, R.M., Konstantinov, V.A., Nakazawa, Y.
Format: Article
Language:English
Published: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2017
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Online Access:https://nasplib.isofts.kiev.ua/handle/123456789/175357
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Journal Title:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Cite this:Thermal expansion of organic superconductor κ-(D₄-BEDT-TTF)₂Cu{N(CN)₂}Br. Isotopic effect / A.V. Dolbin, M.V. Khlistuck, V.B. Eselson, V.G. Gavrilko, N.A. Vinnikov, R.M. Basnukaeva, V.A. Konstantinov, Y. Nakazawa // Физика низких температур. — 2017. — Т. 43, № 12. — С. 1740-1744. — Бібліогр.: 16 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
id nasplib_isofts_kiev_ua-123456789-175357
record_format dspace
spelling Dolbin, A.V.
Khlistuck, M.V.
Eselson, V.B.
Gavrilko, V.G.
Vinnikov, N.A.
Basnukaeva, R.M.
Konstantinov, V.A.
Nakazawa, Y.
2021-01-31T20:34:48Z
2021-01-31T20:34:48Z
2017
Thermal expansion of organic superconductor κ-(D₄-BEDT-TTF)₂Cu{N(CN)₂}Br. Isotopic effect / A.V. Dolbin, M.V. Khlistuck, V.B. Eselson, V.G. Gavrilko, N.A. Vinnikov, R.M. Basnukaeva, V.A. Konstantinov, Y. Nakazawa // Физика низких температур. — 2017. — Т. 43, № 12. — С. 1740-1744. — Бібліогр.: 16 назв. — англ.
0132-6414
PACS: 65.40.De, 63.22.Np
https://nasplib.isofts.kiev.ua/handle/123456789/175357
Linear thermal expansion coefficient (LTEC) of single crystal κ-(D₄-BEDT-TTF)₂Cu[N(CN)₂]Br was studied across the crystal layers in the temperature range 2–290 K using the method of precise capacitive dilatometry. Below Tc = 11.6 K the LTEC of the sample had a small negative value, which is apparently due to the transition from the paramagnetic metal in the superconducting state. There was a bend of temperature dependence of the LTEC, which shows broad peak around 40 K and can be attributed to the elastic lattice anomaly around the end-point of Mott boundary. A sharp jump in the LTEC values and hysteresis was observed in the area of Tg ∼ 75–77 K, what is likely explained by the transition in a glass-like state. The isotope effect in the thermal expansion is discusses, which manifested itself in a shift of the phase transitions in comparison with fully deuterated BEDT-TTF sample.
The authors thank Professor A. Kawamoto at Hokkaido University and Professor H. Taniguchi at Saitama University for their synthesis of partially deuterated molecules. The authors are grateful Professor A. Prokhvatilov for fruitful discussion of result.
en
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
Физика низких температур
Низкоразмерные и неупорядоченные системы
Thermal expansion of organic superconductor κ-(D₄-BEDT-TTF)₂Cu{N(CN)₂}Br. Isotopic effect
Article
published earlier
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
title Thermal expansion of organic superconductor κ-(D₄-BEDT-TTF)₂Cu{N(CN)₂}Br. Isotopic effect
spellingShingle Thermal expansion of organic superconductor κ-(D₄-BEDT-TTF)₂Cu{N(CN)₂}Br. Isotopic effect
Dolbin, A.V.
Khlistuck, M.V.
Eselson, V.B.
Gavrilko, V.G.
Vinnikov, N.A.
Basnukaeva, R.M.
Konstantinov, V.A.
Nakazawa, Y.
Низкоразмерные и неупорядоченные системы
title_short Thermal expansion of organic superconductor κ-(D₄-BEDT-TTF)₂Cu{N(CN)₂}Br. Isotopic effect
title_full Thermal expansion of organic superconductor κ-(D₄-BEDT-TTF)₂Cu{N(CN)₂}Br. Isotopic effect
title_fullStr Thermal expansion of organic superconductor κ-(D₄-BEDT-TTF)₂Cu{N(CN)₂}Br. Isotopic effect
title_full_unstemmed Thermal expansion of organic superconductor κ-(D₄-BEDT-TTF)₂Cu{N(CN)₂}Br. Isotopic effect
title_sort thermal expansion of organic superconductor κ-(d₄-bedt-ttf)₂cu{n(cn)₂}br. isotopic effect
author Dolbin, A.V.
Khlistuck, M.V.
Eselson, V.B.
Gavrilko, V.G.
Vinnikov, N.A.
Basnukaeva, R.M.
Konstantinov, V.A.
Nakazawa, Y.
author_facet Dolbin, A.V.
Khlistuck, M.V.
Eselson, V.B.
Gavrilko, V.G.
Vinnikov, N.A.
Basnukaeva, R.M.
Konstantinov, V.A.
Nakazawa, Y.
topic Низкоразмерные и неупорядоченные системы
topic_facet Низкоразмерные и неупорядоченные системы
publishDate 2017
language English
container_title Физика низких температур
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
format Article
description Linear thermal expansion coefficient (LTEC) of single crystal κ-(D₄-BEDT-TTF)₂Cu[N(CN)₂]Br was studied across the crystal layers in the temperature range 2–290 K using the method of precise capacitive dilatometry. Below Tc = 11.6 K the LTEC of the sample had a small negative value, which is apparently due to the transition from the paramagnetic metal in the superconducting state. There was a bend of temperature dependence of the LTEC, which shows broad peak around 40 K and can be attributed to the elastic lattice anomaly around the end-point of Mott boundary. A sharp jump in the LTEC values and hysteresis was observed in the area of Tg ∼ 75–77 K, what is likely explained by the transition in a glass-like state. The isotope effect in the thermal expansion is discusses, which manifested itself in a shift of the phase transitions in comparison with fully deuterated BEDT-TTF sample.
issn 0132-6414
url https://nasplib.isofts.kiev.ua/handle/123456789/175357
citation_txt Thermal expansion of organic superconductor κ-(D₄-BEDT-TTF)₂Cu{N(CN)₂}Br. Isotopic effect / A.V. Dolbin, M.V. Khlistuck, V.B. Eselson, V.G. Gavrilko, N.A. Vinnikov, R.M. Basnukaeva, V.A. Konstantinov, Y. Nakazawa // Физика низких температур. — 2017. — Т. 43, № 12. — С. 1740-1744. — Бібліогр.: 16 назв. — англ.
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first_indexed 2025-12-07T19:27:48Z
last_indexed 2025-12-07T19:27:48Z
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