Crystalline phase detection in glass ceramics by EPR spectroscopy
The advances of EPR spectroscopy for the detection of activators as well as determining their local structure in the crystalline phase of glass ceramics is considered. The feasibility of d-element (Mn²⁺, Cu²⁺) and f-element(Gd³⁺, Eu²⁺) ion probes for the investigation of glass ceramics is discussed....
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| Datum: | 2018 |
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Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2018
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| Zitieren: | Crystalline phase detection in glass ceramics by EPR spectroscopy / A. Antuzevics, U. Rogulis, A. Fedotovs, A.I. Popov // Физика низких температур. — 2018. — Т. 44, № 4. — С. 449-454. — Бібліогр.: 39 назв. — англ. |
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Antuzevics, A. Rogulis, U. Fedotovs, A. Popov, A.I. 2021-02-03T08:52:20Z 2021-02-03T08:52:20Z 2018 Crystalline phase detection in glass ceramics by EPR spectroscopy / A. Antuzevics, U. Rogulis, A. Fedotovs, A.I. Popov // Физика низких температур. — 2018. — Т. 44, № 4. — С. 449-454. — Бібліогр.: 39 назв. — англ. 0132-6414 PACS: 76.30.–v, 61.72.Hh https://nasplib.isofts.kiev.ua/handle/123456789/175992 The advances of EPR spectroscopy for the detection of activators as well as determining their local structure in the crystalline phase of glass ceramics is considered. The feasibility of d-element (Mn²⁺, Cu²⁺) and f-element(Gd³⁺, Eu²⁺) ion probes for the investigation of glass ceramics is discussed. In the case of Mn²⁺, the informationis obtained from the EPR spectrum superhyperfine structure, for Gd³⁺ and Eu²⁺ probes – from the EPR spectrum fine structure, whereas for Cu²⁺ ions the changes in the EPR spectrum shape could be useful. The examples of EPR spectra of the above-mentioned probes in oxyfluoride glass ceramics are illustrated. The authors thank Meldra Kemere and Dr. Edgars Elsts for sample synthesis and Reinis Ignatans for XRD measurements. Financial support of Latvian-Ukrainian Joint Research Project No. LV-UA/2016/1 is acknowledged. en Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України Физика низких температур Динамика кристаллической решетки Crystalline phase detection in glass ceramics by EPR spectroscopy Article published earlier |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| title |
Crystalline phase detection in glass ceramics by EPR spectroscopy |
| spellingShingle |
Crystalline phase detection in glass ceramics by EPR spectroscopy Antuzevics, A. Rogulis, U. Fedotovs, A. Popov, A.I. Динамика кристаллической решетки |
| title_short |
Crystalline phase detection in glass ceramics by EPR spectroscopy |
| title_full |
Crystalline phase detection in glass ceramics by EPR spectroscopy |
| title_fullStr |
Crystalline phase detection in glass ceramics by EPR spectroscopy |
| title_full_unstemmed |
Crystalline phase detection in glass ceramics by EPR spectroscopy |
| title_sort |
crystalline phase detection in glass ceramics by epr spectroscopy |
| author |
Antuzevics, A. Rogulis, U. Fedotovs, A. Popov, A.I. |
| author_facet |
Antuzevics, A. Rogulis, U. Fedotovs, A. Popov, A.I. |
| topic |
Динамика кристаллической решетки |
| topic_facet |
Динамика кристаллической решетки |
| publishDate |
2018 |
| language |
English |
| container_title |
Физика низких температур |
| publisher |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| format |
Article |
| description |
The advances of EPR spectroscopy for the detection of activators as well as determining their local structure in the crystalline phase of glass ceramics is considered. The feasibility of d-element (Mn²⁺, Cu²⁺) and f-element(Gd³⁺, Eu²⁺) ion probes for the investigation of glass ceramics is discussed. In the case of Mn²⁺, the informationis obtained from the EPR spectrum superhyperfine structure, for Gd³⁺ and Eu²⁺ probes – from the EPR spectrum fine structure, whereas for Cu²⁺ ions the changes in the EPR spectrum shape could be useful. The examples of EPR spectra of the above-mentioned probes in oxyfluoride glass ceramics are illustrated.
|
| issn |
0132-6414 |
| url |
https://nasplib.isofts.kiev.ua/handle/123456789/175992 |
| citation_txt |
Crystalline phase detection in glass ceramics by EPR spectroscopy / A. Antuzevics, U. Rogulis, A. Fedotovs, A.I. Popov // Физика низких температур. — 2018. — Т. 44, № 4. — С. 449-454. — Бібліогр.: 39 назв. — англ. |
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2025-12-07T19:36:03Z |
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2025-12-07T19:36:03Z |
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