Magnetic properties of the spin-1 chain compound NiCl₃C6H5CH₂CH₂NH₃
We report experimental results of the static magnetization, ESR and NMR spectroscopic measurements of the Ni-hybrid compound NiCl₃C6H5CH₂CH₂NH₃. In this material NiCl³ octahedra are structurally arranged in chains along the crystallographic a axis. According to the static susceptibility and ESR data...
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| Published in: | Физика низких температур |
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| Date: | 2018 |
| Main Authors: | , , , , , , , , , |
| Format: | Article |
| Language: | English |
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Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2018
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| Online Access: | https://nasplib.isofts.kiev.ua/handle/123456789/176231 |
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| Journal Title: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Cite this: | Magnetic properties of the spin-1 chain compound NiCl₃C6H5CH₂CH₂NH₃ / F. Lipps, A.H. Arkenbout, A. Polyakov, M. Günther, T. Salikhov, E. Vavilova, H.H. Klauss, B. Büchner, T.M. Palstra, and V. Kataev // Физика низких температур. — 2018. — Т. 44, № 11. — С. 1626-1633. — Бібліогр.: 28 назв. — англ. |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine| _version_ | 1862705030475284480 |
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| author | Lipps, F. Arkenbout, A.H. Polyakov, A. Günther, M. Salikhov, T. Vavilova, E. Klauss, H.H. Büchner, B. Palstra, T.M. Kataev, V. |
| author_facet | Lipps, F. Arkenbout, A.H. Polyakov, A. Günther, M. Salikhov, T. Vavilova, E. Klauss, H.H. Büchner, B. Palstra, T.M. Kataev, V. |
| citation_txt | Magnetic properties of the spin-1 chain compound NiCl₃C6H5CH₂CH₂NH₃ / F. Lipps, A.H. Arkenbout, A. Polyakov, M. Günther, T. Salikhov, E. Vavilova, H.H. Klauss, B. Büchner, T.M. Palstra, and V. Kataev // Физика низких температур. — 2018. — Т. 44, № 11. — С. 1626-1633. — Бібліогр.: 28 назв. — англ. |
| collection | DSpace DC |
| container_title | Физика низких температур |
| description | We report experimental results of the static magnetization, ESR and NMR spectroscopic measurements of the Ni-hybrid compound NiCl₃C6H5CH₂CH₂NH₃. In this material NiCl³ octahedra are structurally arranged in chains along the crystallographic a axis. According to the static susceptibility and ESR data Ni²⁺ spins S = 1 are isotropicand are coupled antiferromagnetically (AFM) along the chain with the exchange constant J = 25.5 K. These are important prerequisites for the realization of the so-called Haldane spin-1 chain with the spin-singlet ground state and a quantum spin gap. However, experimental results evidence AFM order at TN ≈ 10 K presumably due to small interchain couplings. Interestingly, frequency-, magnetic field-, and temperature-dependent ESR measurements, as well as the NMR data, reveal signatures which could presumably indicate an inhomogeneous ground state of coexistent mesoscopically spatially separated AFM ordered and spin-singlet state regions similar to the situation observed before in some spin-diluted Haldane magnets.
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| first_indexed | 2025-12-07T16:52:56Z |
| format | Article |
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| id | nasplib_isofts_kiev_ua-123456789-176231 |
| institution | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| issn | 0132-6414 |
| language | English |
| last_indexed | 2025-12-07T16:52:56Z |
| publishDate | 2018 |
| publisher | Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| record_format | dspace |
| spelling | Lipps, F. Arkenbout, A.H. Polyakov, A. Günther, M. Salikhov, T. Vavilova, E. Klauss, H.H. Büchner, B. Palstra, T.M. Kataev, V. 2021-02-04T07:44:34Z 2021-02-04T07:44:34Z 2018 Magnetic properties of the spin-1 chain compound NiCl₃C6H5CH₂CH₂NH₃ / F. Lipps, A.H. Arkenbout, A. Polyakov, M. Günther, T. Salikhov, E. Vavilova, H.H. Klauss, B. Büchner, T.M. Palstra, and V. Kataev // Физика низких температур. — 2018. — Т. 44, № 11. — С. 1626-1633. — Бібліогр.: 28 назв. — англ. 0132-6414 PACS: 76.30.–v, 76.60.–k, 75.10.Pq, 75.50.Ee https://nasplib.isofts.kiev.ua/handle/123456789/176231 We report experimental results of the static magnetization, ESR and NMR spectroscopic measurements of the Ni-hybrid compound NiCl₃C6H5CH₂CH₂NH₃. In this material NiCl³ octahedra are structurally arranged in chains along the crystallographic a axis. According to the static susceptibility and ESR data Ni²⁺ spins S = 1 are isotropicand are coupled antiferromagnetically (AFM) along the chain with the exchange constant J = 25.5 K. These are important prerequisites for the realization of the so-called Haldane spin-1 chain with the spin-singlet ground state and a quantum spin gap. However, experimental results evidence AFM order at TN ≈ 10 K presumably due to small interchain couplings. Interestingly, frequency-, magnetic field-, and temperature-dependent ESR measurements, as well as the NMR data, reveal signatures which could presumably indicate an inhomogeneous ground state of coexistent mesoscopically spatially separated AFM ordered and spin-singlet state regions similar to the situation observed before in some spin-diluted Haldane magnets. This work was supported in parts by the Deutsche
 Forschungsgemeinschaft (DFG) through projects FOR912
 and KA 1694/8-1, by the Dieptestrategie of the Zernike Institute for Advanced Materials, and by the Erasmus + ICM
 Program of the European Union. en Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України Физика низких температур Специальный выпуск К 80-летию со дня рождения А.И. Звягина Magnetic properties of the spin-1 chain compound NiCl₃C6H5CH₂CH₂NH₃ Article published earlier |
| spellingShingle | Magnetic properties of the spin-1 chain compound NiCl₃C6H5CH₂CH₂NH₃ Lipps, F. Arkenbout, A.H. Polyakov, A. Günther, M. Salikhov, T. Vavilova, E. Klauss, H.H. Büchner, B. Palstra, T.M. Kataev, V. Специальный выпуск К 80-летию со дня рождения А.И. Звягина |
| title | Magnetic properties of the spin-1 chain compound NiCl₃C6H5CH₂CH₂NH₃ |
| title_full | Magnetic properties of the spin-1 chain compound NiCl₃C6H5CH₂CH₂NH₃ |
| title_fullStr | Magnetic properties of the spin-1 chain compound NiCl₃C6H5CH₂CH₂NH₃ |
| title_full_unstemmed | Magnetic properties of the spin-1 chain compound NiCl₃C6H5CH₂CH₂NH₃ |
| title_short | Magnetic properties of the spin-1 chain compound NiCl₃C6H5CH₂CH₂NH₃ |
| title_sort | magnetic properties of the spin-1 chain compound nicl₃c6h5ch₂ch₂nh₃ |
| topic | Специальный выпуск К 80-летию со дня рождения А.И. Звягина |
| topic_facet | Специальный выпуск К 80-летию со дня рождения А.И. Звягина |
| url | https://nasplib.isofts.kiev.ua/handle/123456789/176231 |
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