Electron-impact desorption of metastable particles from CO films
The impact of monochromatic low-energy electrons (4–52 eV) is found to induce desorption of metastable particles (MP) from multilayer films formed by condensing CO gas on a Pt(111) substrate held at 20 K. The results are compared with metastable production from gaseous CO. Metastable CO (CO*) is ide...
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| Опубліковано в: : | Физика низких температур |
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| Дата: | 1998 |
| Автори: | , , |
| Формат: | Стаття |
| Мова: | Англійська |
| Опубліковано: |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
1998
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| Онлайн доступ: | https://nasplib.isofts.kiev.ua/handle/123456789/176657 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Electron-impact desorption of metastable particles from CO films / H. Shi, P. Cloutier, L. Sanche // Физика низких температур. — 1998. — Т. 24, № 10. — С. 984-991. — Бібліогр.: 44 назв. — англ. |
Репозитарії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| _version_ | 1862740578990555136 |
|---|---|
| author | Shi, H. Cloutier, P. Sanche, L. |
| author_facet | Shi, H. Cloutier, P. Sanche, L. |
| citation_txt | Electron-impact desorption of metastable particles from CO films / H. Shi, P. Cloutier, L. Sanche // Физика низких температур. — 1998. — Т. 24, № 10. — С. 984-991. — Бібліогр.: 44 назв. — англ. |
| collection | DSpace DC |
| container_title | Физика низких температур |
| description | The impact of monochromatic low-energy electrons (4–52 eV) is found to induce desorption of metastable particles (MP) from multilayer films formed by condensing CO gas on a Pt(111) substrate held at 20 K. The results are compared with metastable production from gaseous CO. Metastable CO (CO*) is identified as the major desorbed species, its desorption is discussed in terms of intramolecular to molecule-surface vibrational energy transfer. Primary electronic excitation proceeds via the states, a'³Σ⁺, d³Δ, e³Σ⁻, I¹Σ⁻, and D¹Δ which contribute to MP desorption directly or by first decaying in high vibrational levels of the a³Π configuration. The energy threshold of 8.0 eV for CO* desorption indicates that CO in low vibrational levels of the a³Π state does not desorb. Electronic excitation occurs either near the surface of the CO film or in the bulk. In the latter case, excitonic motion to the surface can be followed by CO* desorption.
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| first_indexed | 2025-12-07T20:15:26Z |
| format | Article |
| fulltext | |
| id | nasplib_isofts_kiev_ua-123456789-176657 |
| institution | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| issn | 0132-6414 |
| language | English |
| last_indexed | 2025-12-07T20:15:26Z |
| publishDate | 1998 |
| publisher | Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| record_format | dspace |
| spelling | Shi, H. Cloutier, P. Sanche, L. 2021-02-06T14:55:58Z 2021-02-06T14:55:58Z 1998 Electron-impact desorption of metastable particles from CO films / H. Shi, P. Cloutier, L. Sanche // Физика низких температур. — 1998. — Т. 24, № 10. — С. 984-991. — Бібліогр.: 44 назв. — англ. 0132-6414 PACS: 34.80.Gs, 79.20.Kz https://nasplib.isofts.kiev.ua/handle/123456789/176657 The impact of monochromatic low-energy electrons (4–52 eV) is found to induce desorption of metastable particles (MP) from multilayer films formed by condensing CO gas on a Pt(111) substrate held at 20 K. The results are compared with metastable production from gaseous CO. Metastable CO (CO*) is identified as the major desorbed species, its desorption is discussed in terms of intramolecular to molecule-surface vibrational energy transfer. Primary electronic excitation proceeds via the states, a'³Σ⁺, d³Δ, e³Σ⁻, I¹Σ⁻, and D¹Δ which contribute to MP desorption directly or by first decaying in high vibrational levels of the a³Π configuration. The energy threshold of 8.0 eV for CO* desorption indicates that CO in low vibrational levels of the a³Π state does not desorb. Electronic excitation occurs either near the surface of the CO film or in the bulk. In the latter case, excitonic motion to the surface can be followed by CO* desorption. This work was sponsored by the Medical Re-search Council of Canada. en Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України Физика низких температур Физические свойства криокристаллов Electron-impact desorption of metastable particles from CO films Article published earlier |
| spellingShingle | Electron-impact desorption of metastable particles from CO films Shi, H. Cloutier, P. Sanche, L. Физические свойства криокристаллов |
| title | Electron-impact desorption of metastable particles from CO films |
| title_full | Electron-impact desorption of metastable particles from CO films |
| title_fullStr | Electron-impact desorption of metastable particles from CO films |
| title_full_unstemmed | Electron-impact desorption of metastable particles from CO films |
| title_short | Electron-impact desorption of metastable particles from CO films |
| title_sort | electron-impact desorption of metastable particles from co films |
| topic | Физические свойства криокристаллов |
| topic_facet | Физические свойства криокристаллов |
| url | https://nasplib.isofts.kiev.ua/handle/123456789/176657 |
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