Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes.
A theoretical model is proposed, which describes the mechanism of the anodic dissolution of metals in multicomponent electrolytes. The relation between chemical reaction and transport processes may give rise to two stable states in the electrochemical system. It has been shown that in the case of co...
Gespeichert in:
| Veröffentlicht in: | Украинский химический журнал |
|---|---|
| Datum: | 2005 |
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | Englisch |
| Veröffentlicht: |
Інститут загальної та неорганічної хімії ім. В.І. Вернадського НАН України
2005
|
| Schlagworte: | |
| Online Zugang: | https://nasplib.isofts.kiev.ua/handle/123456789/184079 |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Zitieren: | Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. / V.V. Pototskaya, S.V. Volkov, A.A. Omel’chuk // Украинский химический журнал. — 2005. — Т. 71, № 11-12. — С. 116-120. — Бібліогр.: 10 назв. — англ. |
Institution
Digital Library of Periodicals of National Academy of Sciences of Ukraine| _version_ | 1862668519511949312 |
|---|---|
| author | Pototskaya, V.V. Volkov, S.V. Omel’chuk, A.A. |
| author_facet | Pototskaya, V.V. Volkov, S.V. Omel’chuk, A.A. |
| citation_txt | Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. / V.V. Pototskaya, S.V. Volkov, A.A. Omel’chuk // Украинский химический журнал. — 2005. — Т. 71, № 11-12. — С. 116-120. — Бібліогр.: 10 назв. — англ. |
| collection | DSpace DC |
| container_title | Украинский химический журнал |
| description | A theoretical model is proposed, which describes the mechanism of the anodic dissolution of metals in multicomponent electrolytes. The relation between chemical reaction and transport processes may give rise to two stable states in the electrochemical system. It has been shown that in the case of controlling the rate of the mass transfer process in electrochemical systems with a number of components of ≥ 3, the outer Helmholtz plane potential may take on two values at the same electrode potential value. The question of the appearance of anodic dissolution limiting currents has been studied for electrolytes containing four sorts of ions with arbitrary charges and diffusion coefficients. The existence and magnitude of limiting current are also dependent on the charge of the complex formed.
|
| first_indexed | 2025-12-07T15:25:01Z |
| format | Article |
| fulltext | |
| id | nasplib_isofts_kiev_ua-123456789-184079 |
| institution | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| issn | 0041–6045 |
| language | English |
| last_indexed | 2025-12-07T15:25:01Z |
| publishDate | 2005 |
| publisher | Інститут загальної та неорганічної хімії ім. В.І. Вернадського НАН України |
| record_format | dspace |
| spelling | Pototskaya, V.V. Volkov, S.V. Omel’chuk, A.A. 2022-05-04T11:04:35Z 2022-05-04T11:04:35Z 2005 Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. / V.V. Pototskaya, S.V. Volkov, A.A. Omel’chuk // Украинский химический журнал. — 2005. — Т. 71, № 11-12. — С. 116-120. — Бібліогр.: 10 назв. — англ. 0041–6045 https://nasplib.isofts.kiev.ua/handle/123456789/184079 A theoretical model is proposed, which describes the mechanism of the anodic dissolution of metals in multicomponent electrolytes. The relation between chemical reaction and transport processes may give rise to two stable states in the electrochemical system. It has been shown that in the case of controlling the rate of the mass transfer process in electrochemical systems with a number of components of ≥ 3, the outer Helmholtz plane potential may take on two values at the same electrode potential value. The question of the appearance of anodic dissolution limiting currents has been studied for electrolytes containing four sorts of ions with arbitrary charges and diffusion coefficients. The existence and magnitude of limiting current are also dependent on the charge of the complex formed. en Інститут загальної та неорганічної хімії ім. В.І. Вернадського НАН України Украинский химический журнал Неорганическая и физическая химия Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. Природа бистабильных состояний при анодном растворении металлов в многокомпонентных электролигах Природа бістабільних станів при анодному розчиненні металів у багатокомпонентних електролітах Article published earlier |
| spellingShingle | Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. Pototskaya, V.V. Volkov, S.V. Omel’chuk, A.A. Неорганическая и физическая химия |
| title | Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. |
| title_alt | Природа бистабильных состояний при анодном растворении металлов в многокомпонентных электролигах Природа бістабільних станів при анодному розчиненні металів у багатокомпонентних електролітах |
| title_full | Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. |
| title_fullStr | Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. |
| title_full_unstemmed | Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. |
| title_short | Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. |
| title_sort | nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. |
| topic | Неорганическая и физическая химия |
| topic_facet | Неорганическая и физическая химия |
| url | https://nasplib.isofts.kiev.ua/handle/123456789/184079 |
| work_keys_str_mv | AT pototskayavv natureofbistablestatesinthecaseofanodicdissolutionofmetalsinmulticomponentelectrolytes AT volkovsv natureofbistablestatesinthecaseofanodicdissolutionofmetalsinmulticomponentelectrolytes AT omelchukaa natureofbistablestatesinthecaseofanodicdissolutionofmetalsinmulticomponentelectrolytes AT pototskayavv prirodabistabilʹnyhsostoâniiprianodnomrastvoreniimetallovvmnogokomponentnyhélektroligah AT volkovsv prirodabistabilʹnyhsostoâniiprianodnomrastvoreniimetallovvmnogokomponentnyhélektroligah AT omelchukaa prirodabistabilʹnyhsostoâniiprianodnomrastvoreniimetallovvmnogokomponentnyhélektroligah AT pototskayavv prirodabístabílʹnihstanívprianodnomurozčinennímetalívubagatokomponentnihelektrolítah AT volkovsv prirodabístabílʹnihstanívprianodnomurozčinennímetalívubagatokomponentnihelektrolítah AT omelchukaa prirodabístabílʹnihstanívprianodnomurozčinennímetalívubagatokomponentnihelektrolítah |