Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes.
A theoretical model is proposed, which describes the mechanism of the anodic dissolution of metals in multicomponent electrolytes. The relation between chemical reaction and transport processes may give rise to two stable states in the electrochemical system. It has been shown that in the case of co...
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| Published in: | Украинский химический журнал |
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| Date: | 2005 |
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| Format: | Article |
| Language: | English |
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Інститут загальної та неорганічної хімії ім. В.І. Вернадського НАН України
2005
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| Online Access: | https://nasplib.isofts.kiev.ua/handle/123456789/184079 |
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| Cite this: | Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. / V.V. Pototskaya, S.V. Volkov, A.A. Omel’chuk // Украинский химический журнал. — 2005. — Т. 71, № 11-12. — С. 116-120. — Бібліогр.: 10 назв. — англ. |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine| id |
nasplib_isofts_kiev_ua-123456789-184079 |
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Pototskaya, V.V. Volkov, S.V. Omel’chuk, A.A. 2022-05-04T11:04:35Z 2022-05-04T11:04:35Z 2005 Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. / V.V. Pototskaya, S.V. Volkov, A.A. Omel’chuk // Украинский химический журнал. — 2005. — Т. 71, № 11-12. — С. 116-120. — Бібліогр.: 10 назв. — англ. 0041–6045 https://nasplib.isofts.kiev.ua/handle/123456789/184079 A theoretical model is proposed, which describes the mechanism of the anodic dissolution of metals in multicomponent electrolytes. The relation between chemical reaction and transport processes may give rise to two stable states in the electrochemical system. It has been shown that in the case of controlling the rate of the mass transfer process in electrochemical systems with a number of components of ≥ 3, the outer Helmholtz plane potential may take on two values at the same electrode potential value. The question of the appearance of anodic dissolution limiting currents has been studied for electrolytes containing four sorts of ions with arbitrary charges and diffusion coefficients. The existence and magnitude of limiting current are also dependent on the charge of the complex formed. en Інститут загальної та неорганічної хімії ім. В.І. Вернадського НАН України Украинский химический журнал Неорганическая и физическая химия Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. Природа бистабильных состояний при анодном растворении металлов в многокомпонентных электролигах Природа бістабільних станів при анодному розчиненні металів у багатокомпонентних електролітах Article published earlier |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| title |
Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. |
| spellingShingle |
Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. Pototskaya, V.V. Volkov, S.V. Omel’chuk, A.A. Неорганическая и физическая химия |
| title_short |
Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. |
| title_full |
Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. |
| title_fullStr |
Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. |
| title_full_unstemmed |
Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. |
| title_sort |
nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. |
| author |
Pototskaya, V.V. Volkov, S.V. Omel’chuk, A.A. |
| author_facet |
Pototskaya, V.V. Volkov, S.V. Omel’chuk, A.A. |
| topic |
Неорганическая и физическая химия |
| topic_facet |
Неорганическая и физическая химия |
| publishDate |
2005 |
| language |
English |
| container_title |
Украинский химический журнал |
| publisher |
Інститут загальної та неорганічної хімії ім. В.І. Вернадського НАН України |
| format |
Article |
| title_alt |
Природа бистабильных состояний при анодном растворении металлов в многокомпонентных электролигах Природа бістабільних станів при анодному розчиненні металів у багатокомпонентних електролітах |
| description |
A theoretical model is proposed, which describes the mechanism of the anodic dissolution of metals in multicomponent electrolytes. The relation between chemical reaction and transport processes may give rise to two stable states in the electrochemical system. It has been shown that in the case of controlling the rate of the mass transfer process in electrochemical systems with a number of components of ≥ 3, the outer Helmholtz plane potential may take on two values at the same electrode potential value. The question of the appearance of anodic dissolution limiting currents has been studied for electrolytes containing four sorts of ions with arbitrary charges and diffusion coefficients. The existence and magnitude of limiting current are also dependent on the charge of the complex formed.
|
| issn |
0041–6045 |
| url |
https://nasplib.isofts.kiev.ua/handle/123456789/184079 |
| citation_txt |
Nature of bistable states in the case of anodic dissolution of metals in multicomponent electrolytes. / V.V. Pototskaya, S.V. Volkov, A.A. Omel’chuk // Украинский химический журнал. — 2005. — Т. 71, № 11-12. — С. 116-120. — Бібліогр.: 10 назв. — англ. |
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| first_indexed |
2025-12-07T15:25:01Z |
| last_indexed |
2025-12-07T15:25:01Z |
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