Structure, spectroscopic and thermal characterization of bis(acetylacetonato) dichlorotin (IV) synthesized in aqueous solution

• Datum: 2010
• Hauptverfasser: Ulug, B., Turkdemir, H.M., Ulug, A., Buyukgungor, O., Yucel, M.B., Smyntyna, V.A., Grinevich, V.S., Filevskaya, L.N.
• Format: Artikel
• Sprache: English
• Veröffentlicht: Інститут загальної та неорганічної хімії ім. В.І. Вернадського НАН України 2010
• Schriftenreihe: Украинский химический журнал
• Schlagworte: Неорганическая и физическая химия
• Online Zugang: https://nasplib.isofts.kiev.ua/handle/123456789/186054
• Назва журналу: Digital Library of Periodicals of National Academy of Sciences of Ukraine
• Zitieren: Structure, spectroscopic and thermal characterization of bis(acetylacetonato) dichlorotin (IV) synthesized in aqueous solution / B. Ulug, H.M. Turkdemir, A. Ulug, O. Buyukgungor, M.B. Yucel, V.A. Smyntyna, V.S. Grinevich, L.N. Filevskaya // Украинский химический журнал. — 2010. — Т. 76, № 7. — С. 12-17. — Бібліогр.: 36 назв. — англ.

Bis(acetylacetonato)dichlorotin(IV) is synthesized from the aqueous solutions of tin(IV) chloride and acetylacetone followed by vacuum drying at room temperature. DTA/TGA, FTIR, UV-VIS, X-ray powder and single crystal, mass spectra and elemental analysis are performed to characterize the product. X-ray powder diffraction suggests that the sample may contain some impurities such as SnO, SnO₂ and Sn₂О₃ while the mass spectra indicates the existence of Sn(acac)₄, which is arguable due to the steric effect. Single crystal investigation reveals that the product synthesized in aqueous solution is Sn(acac)₂Cl₂, crystallized in monoclinic system in space group C2/c with unit cell constants a=13.983(2), b=7.8928(8), c=13.7889(19) Å and β =107.601(11)°, whose volume is 1.43 % smaller than the one synthesized in dry toluene.