Peroxyhydrocarbonate and peroxocarbonate ions as typical α-nucleophiles in phosphonyl transfer

• Published in: Украинский химический журнал
• Date: 2011
• Main Authors: Prokop’eva, T.M., Sadovskii, Yu.S., Savyolova, V.A., Solomoichenko, T.N., Piskunova, Zh.P., Bunton, C.A., Popov, A.F.
• Format: Article
• Language: English
• Published: Інститут загальної та неорганічної хімії ім. В.І. Вернадського НАН України 2011
• Subjects: Органическая химия
• Online Access: https://nasplib.isofts.kiev.ua/handle/123456789/186229
• Journal Title: Digital Library of Periodicals of National Academy of Sciences of Ukraine
• Cite this: Peroxyhydrocarbonate and peroxocarbonate ions as typical α-nucleophiles in phosphonyl transfer / T.M. Prokop’eva, Yu.S. Sadovskii, V.A. Savyolova, T.N. Solomoichenko, Zh.P. Piskunova, C.A. Bunton, A.F. Popov // Украинский химический журнал. — 2011. — Т. 77, № 1. — С. 54-60. — Бібліогр.: 31 назв. — англ.

In a search for novel, high-reactivity, α-nucleophiles we examined the kinetics of decomposition of 4-nitrophenyldiethyl phosphonate (NPDEPN) by Н₂О₂/NH₄HCO₃/HО⁻ at рН 7.7—10.4. This system generates HCO₄⁻ and CO₄²⁻, and their equilibrium concentrations were calculated with the corresponding equilib...