Synthesis and characterisation of new potassium-containing argyrodite-type compounds

Potassium halogen thiophosphates K₆PS₅Br and K₆PS₅Cl, as well as halogen-free K₇PS₆ compound, were synthesized using the two-step technique from elemental substances as well as potassium halides. The elemental composition of the obtained samples was determined using energy-dispersive X-ray spectrosc...

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Veröffentlicht in:Semiconductor Physics Quantum Electronics & Optoelectronics
Datum:2019
Hauptverfasser: Studenyak, I.P., Pogodin, A.I., Studenyak, V.I., Kokhan, O.P., Azhniuk, Yu.M., Cserhati, C., Kokenyesi, S., Zahn, D. R.T.
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Sprache:Englisch
Veröffentlicht: Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України 2019
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Online Zugang:https://nasplib.isofts.kiev.ua/handle/123456789/215431
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Zitieren:Synthesis and characterisation of new potassium-containing argyrodite-type compounds / I.P. Studenyak, A.I. Pogodin, V.I. Studenyak, O.P. Kokhan, Yu.M. Azhniuk, C. Cserhati, S. Kokenyesi, D. R.T. Zahn // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2019. — Т. 22, № 1. — С. 26-33. — Бібліогр.: 26 назв. — англ.

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author Studenyak, I.P.
Pogodin, A.I.
Studenyak, V.I.
Kokhan, O.P.
Azhniuk, Yu.M.
Cserhati, C.
Kokenyesi, S.
Zahn, D. R.T.
author_facet Studenyak, I.P.
Pogodin, A.I.
Studenyak, V.I.
Kokhan, O.P.
Azhniuk, Yu.M.
Cserhati, C.
Kokenyesi, S.
Zahn, D. R.T.
citation_txt Synthesis and characterisation of new potassium-containing argyrodite-type compounds / I.P. Studenyak, A.I. Pogodin, V.I. Studenyak, O.P. Kokhan, Yu.M. Azhniuk, C. Cserhati, S. Kokenyesi, D. R.T. Zahn // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2019. — Т. 22, № 1. — С. 26-33. — Бібліогр.: 26 назв. — англ.
collection DSpace DC
container_title Semiconductor Physics Quantum Electronics & Optoelectronics
description Potassium halogen thiophosphates K₆PS₅Br and K₆PS₅Cl, as well as halogen-free K₇PS₆ compound, were synthesized using the two-step technique from elemental substances as well as potassium halides. The elemental composition of the obtained samples was determined using energy-dispersive X-ray spectroscopy. Raman spectra of K₆PS₅Br and K₆PS₅Cl show themselves to be very similar to those of chemically related Cu₆PS₅Br and Cu₆PS₅Cl argyrodite crystals. The much richer spectra of K₆PS₅Br and K₆PS₅Cl, as well as K₇PS₆, however, reveal that their structure most likely differs from the cubic structure of Cu₆PS₅Br and Cu₆PS₅Cl argyrodites.
first_indexed 2026-03-23T18:51:36Z
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language English
last_indexed 2026-03-23T18:51:36Z
publishDate 2019
publisher Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
record_format dspace
spelling Studenyak, I.P.
Pogodin, A.I.
Studenyak, V.I.
Kokhan, O.P.
Azhniuk, Yu.M.
Cserhati, C.
Kokenyesi, S.
Zahn, D. R.T.
2026-03-16T11:01:17Z
2019
Synthesis and characterisation of new potassium-containing argyrodite-type compounds / I.P. Studenyak, A.I. Pogodin, V.I. Studenyak, O.P. Kokhan, Yu.M. Azhniuk, C. Cserhati, S. Kokenyesi, D. R.T. Zahn // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2019. — Т. 22, № 1. — С. 26-33. — Бібліогр.: 26 назв. — англ.
1560-8034
PACS: 78.40.Ha; 77.80.Bh
https://nasplib.isofts.kiev.ua/handle/123456789/215431
https://doi.org/10.15407/spqeo22.01.26
Potassium halogen thiophosphates K₆PS₅Br and K₆PS₅Cl, as well as halogen-free K₇PS₆ compound, were synthesized using the two-step technique from elemental substances as well as potassium halides. The elemental composition of the obtained samples was determined using energy-dispersive X-ray spectroscopy. Raman spectra of K₆PS₅Br and K₆PS₅Cl show themselves to be very similar to those of chemically related Cu₆PS₅Br and Cu₆PS₅Cl argyrodite crystals. The much richer spectra of K₆PS₅Br and K₆PS₅Cl, as well as K₇PS₆, however, reveal that their structure most likely differs from the cubic structure of Cu₆PS₅Br and Cu₆PS₅Cl argyrodites.
Yu.M. Azhniuk is grateful to DFG Research Unit FOR 1154 “Towards Molecular Spintronics” for the financial support of his research at Chemnitz University of Technology.
en
Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
Semiconductor Physics Quantum Electronics & Optoelectronics
Semiconductor physics
Synthesis and characterisation of new potassium-containing argyrodite-type compounds
Article
published earlier
spellingShingle Synthesis and characterisation of new potassium-containing argyrodite-type compounds
Studenyak, I.P.
Pogodin, A.I.
Studenyak, V.I.
Kokhan, O.P.
Azhniuk, Yu.M.
Cserhati, C.
Kokenyesi, S.
Zahn, D. R.T.
Semiconductor physics
title Synthesis and characterisation of new potassium-containing argyrodite-type compounds
title_full Synthesis and characterisation of new potassium-containing argyrodite-type compounds
title_fullStr Synthesis and characterisation of new potassium-containing argyrodite-type compounds
title_full_unstemmed Synthesis and characterisation of new potassium-containing argyrodite-type compounds
title_short Synthesis and characterisation of new potassium-containing argyrodite-type compounds
title_sort synthesis and characterisation of new potassium-containing argyrodite-type compounds
topic Semiconductor physics
topic_facet Semiconductor physics
url https://nasplib.isofts.kiev.ua/handle/123456789/215431
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