Взаємодія оксиду нікелю (II) з фосфато-фторидною системою літію
The interaction of nickel dioxide with solutions-melts of the system LiPO3−LiF has been stu- died. Phase formation of LiNi2P3O10, Li2Ni3(P2O7)2, LiNiPO4, and Li2NiPO4F is establi- shed. Synthesized complex phosphates are investigated by X-ray phase analysis, IR-spectroscopy, and quantitative chem...
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| Date: | 2007 |
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| Main Authors: | , , , , , |
| Format: | Article |
| Language: | Ukrainian |
| Published: |
Видавничий дім "Академперіодика" НАН України
2007
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| Subjects: | |
| Online Access: | https://nasplib.isofts.kiev.ua/handle/123456789/3144 |
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| Journal Title: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Cite this: | Взаємодія оксиду нікелю (II) з фосфато-фторидною системою літію / П.Г. Нагорний, З.І. Корнієнко, Р.С. Бойко, Н.О. Городилова, В.М. Баумер, М.С. Слободяник // Доп. НАН України. — 2007. — № 9. — С. 120-125. — Бібліогр.: 12 назв. — укp. |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine| Summary: | The interaction of nickel dioxide with solutions-melts of the system LiPO3−LiF has been stu-
died. Phase formation of LiNi2P3O10, Li2Ni3(P2O7)2, LiNiPO4, and Li2NiPO4F is establi-
shed. Synthesized complex phosphates are investigated by X-ray phase analysis, IR-spectroscopy,
and quantitative chemical analysis. The structure of Li2Ni3(P2O7)2 has been determined from
single-crystal X-ray diffraction data. It crystallizes in the monocline syngony with unit-cell
parameters a = 7.1992(45)˚ A, b = 7.7541(10)˚ A, c = 9.3415(48)˚ A, β = 110.34(5)
◦
, V = 488.96(976)˚ A3
, and space group P21/с.
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| ISSN: | 1025-6415 |