Phase equilibria of size- and charge-asymmetric primitive models of ionic fluids: the method of collective variables

• Published in: Condensed Matter Physics
• Date: 2010
• Main Authors: Patsahan, O.V., Patsahan, T.M.
• Format: Article
• Language: English
• Published: Інститут фізики конденсованих систем НАН України 2010
• Online Access: https://nasplib.isofts.kiev.ua/handle/123456789/32090
• Journal Title: Digital Library of Periodicals of National Academy of Sciences of Ukraine
• Cite this: Phase equilibria of size- and charge-asymmetric primitive models of ionic fluids: the method of collective variables / O.V. Patsahan, T.M. Patsahan // Condensed Matter Physics. — 2010. — Т. 13, № 2. — С. 23004: 1-10. — Бібліогр.: 32 назв. — англ.

We study the phase diagrams of z:1 size-asymmetric primitive models (PMs) using a theory that exploits the method of collective variables. Based on the explicit expression for the relevant chemical potential (conjugate to the order parameter) which includes the correlation effects up to the third or...