Бiс(N-фенiлантранiлати) металiв в обривi ланцюгiв окиснення органiчних сполук
It is shown that bis(N-phenylanthranilates) of metals ML2 (M = Mg, Ca, Sr, Ba) terminate
 the chains of oxidation of organic compounds by the reaction of peroxide radicals with co-
 ordinated > NH- and > N · -groups. At the oxidation of ethylbenzene (90 ◦
 С), the rates...
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| Date: | 2007 |
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| Main Authors: | , , |
| Format: | Article |
| Language: | Ukrainian |
| Published: |
Видавничий дім "Академперіодика" НАН України
2007
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| Subjects: | |
| Online Access: | https://nasplib.isofts.kiev.ua/handle/123456789/3249 |
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| Journal Title: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Cite this: | Біс(N-фенілантранілати) металів в обриві ланцюгів окиснення органічних сполук / О.В. Суховєєв, Г.О. Ковтун, В.В. Суховєєв // Доп. НАН України. — 2007. — № 10. — С. 138-141. — Бібліогр.: 3 назв. — укp. |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine| Summary: | It is shown that bis(N-phenylanthranilates) of metals ML2 (M = Mg, Ca, Sr, Ba) terminate
the chains of oxidation of organic compounds by the reaction of peroxide radicals with co-
ordinated > NH- and > N · -groups. At the oxidation of ethylbenzene (90 ◦
С), the rates of the
reaction (C6H5CH(OO·)CH3+ML2) are measured: (3.8±0.2) · 104
(Ba), (2.8±0.3) · 104
(Ca),
(1.2 ± 1) · 104
(Sr), (0.8 ± 0.1) · 104
l/(mol · s)(Mg).
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| ISSN: | 1025-6415 |