Вплив карбоксиметилцелюлози на електрохiмiчну та корозiйну поведiнку залiза у сiрчанокислих електролiтах

Addition of carboxymethylcellulose to sulfate electrolytes leads to a decrease of the corrosive destruction rate of iron (steel). It is due to the formation of a barrier layer on the iron electrode surface. Such a layer consists of little soluble products of co-operation of carboxymethylcellulose wi...

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Bibliographic Details
Date:2008
Main Authors: Вишневська, Ю.П., Ткаленко, Д.А.
Format: Article
Language:Ukrainian
Published: Видавничий дім "Академперіодика" НАН України 2008
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Online Access:https://nasplib.isofts.kiev.ua/handle/123456789/4646
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Journal Title:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Cite this:Вплив карбоксиметилцелюлози на електрохiмiчну та корозiйну поведiнку залiза у сiрчанокислих електролiтах / Ю.П. Вишневська, Д.А. Ткаленко // Доп. НАН України. — 2008. — № 5. — С. 141-146. — Бібліогр.: 15 назв. — укр.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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Summary:Addition of carboxymethylcellulose to sulfate electrolytes leads to a decrease of the corrosive destruction rate of iron (steel). It is due to the formation of a barrier layer on the iron electrode surface. Such a layer consists of little soluble products of co-operation of carboxymethylcellulose with iron cations, which appear near the electrode/electrolyte interface. A ground of the thesis that the formation of protective layers is conditioned in many cases by the co-operating of organic inhibitors with cations of dissolved metals is brought. In accordance with such a supposition at the choice of organic inhibitors, it is necessary to take into account the stability constant of the appearing metalorganic compounds (complexes) and their solubility in the examined environment.
ISSN:1025-6415