Electrical properties of ZrO₂ in nano- and polycrystalline states at high pressure

We present the results of the research work devoted to the problem: how the crystallites influence the electrical properties of stabilized zirconia at pressures of 22−50 GPa and in the temperature range of 77−450 K. The measurements were conducted in the highpressure chamber under direct current on...

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Опубліковано в: :Физика и техника высоких давлений
Дата:2007
Автори: Korionov, I.V., Trefilova, A.N., Babushkin, A.N., Korionova, I.G., Shumina, U.N., Lojkowski, W., Opalinska, A.
Формат: Стаття
Мова:Англійська
Опубліковано: Донецький фізико-технічний інститут ім. О.О. Галкіна НАН України 2007
Онлайн доступ:https://nasplib.isofts.kiev.ua/handle/123456789/70292
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Electrical properties of ZrO₂ in nano- and polycrystalline states at high pressure / I.V. Korionov, A.N. Trefilova, A.N. Babushkin, I.G. Korionova, U.N. Shumina, W. Lojkowski, A. Opalinska // Физика и техника высоких давлений. — 2007. — Т. 17, № 1. — С. 70-73. — Бібліогр.: 3 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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author Korionov, I.V.
Trefilova, A.N.
Babushkin, A.N.
Korionova, I.G.
Shumina, U.N.
Lojkowski, W.
Opalinska, A.
author_facet Korionov, I.V.
Trefilova, A.N.
Babushkin, A.N.
Korionova, I.G.
Shumina, U.N.
Lojkowski, W.
Opalinska, A.
citation_txt Electrical properties of ZrO₂ in nano- and polycrystalline states at high pressure / I.V. Korionov, A.N. Trefilova, A.N. Babushkin, I.G. Korionova, U.N. Shumina, W. Lojkowski, A. Opalinska // Физика и техника высоких давлений. — 2007. — Т. 17, № 1. — С. 70-73. — Бібліогр.: 3 назв. — англ.
collection DSpace DC
container_title Физика и техника высоких давлений
description We present the results of the research work devoted to the problem: how the crystallites influence the electrical properties of stabilized zirconia at pressures of 22−50 GPa and in the temperature range of 77−450 K. The measurements were conducted in the highpressure chamber under direct current on nanocrystalline powders of ZrO₂ stabilized by Pr (0.5%) and on compact powder samples of «partially stabilized» ZrO₂ including 5% Y₃P₃. The nanocrystallite size equals 10, 12 and 56 nm. The change of electronic properties of stabilized zirconia at 31.5–37.5 GPa, 40–44 GPa and 45.5–48.5 GPa in nano- and polycrystalline states has been discovered. It gives us a possibility to verify the phase diagram of ZrO₂ at those intervals of pressure. Besides, it has been revealed that stabilization as nanocrystallinity leads to appearance of additional mechanisms of conductivity in ZrO₂.
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last_indexed 2025-11-26T00:17:37Z
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publisher Донецький фізико-технічний інститут ім. О.О. Галкіна НАН України
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spelling Korionov, I.V.
Trefilova, A.N.
Babushkin, A.N.
Korionova, I.G.
Shumina, U.N.
Lojkowski, W.
Opalinska, A.
2014-11-02T08:21:44Z
2014-11-02T08:21:44Z
2007
Electrical properties of ZrO₂ in nano- and polycrystalline states at high pressure / I.V. Korionov, A.N. Trefilova, A.N. Babushkin, I.G. Korionova, U.N. Shumina, W. Lojkowski, A. Opalinska // Физика и техника высоких давлений. — 2007. — Т. 17, № 1. — С. 70-73. — Бібліогр.: 3 назв. — англ.
0868-5924
PACS: 71.30.+h, 72.20.−i, 73.63.Bd
https://nasplib.isofts.kiev.ua/handle/123456789/70292
We present the results of the research work devoted to the problem: how the crystallites influence the electrical properties of stabilized zirconia at pressures of 22−50 GPa and in the temperature range of 77−450 K. The measurements were conducted in the highpressure chamber under direct current on nanocrystalline powders of ZrO₂ stabilized by Pr (0.5%) and on compact powder samples of «partially stabilized» ZrO₂ including 5% Y₃P₃. The nanocrystallite size equals 10, 12 and 56 nm. The change of electronic properties of stabilized zirconia at 31.5–37.5 GPa, 40–44 GPa and 45.5–48.5 GPa in nano- and polycrystalline states has been discovered. It gives us a possibility to verify the phase diagram of ZrO₂ at those intervals of pressure. Besides, it has been revealed that stabilization as nanocrystallinity leads to appearance of additional mechanisms of conductivity in ZrO₂.
The research was made possible in part by grants RBRF No.01-03-96494 and CRDF No. REC-005.
en
Донецький фізико-технічний інститут ім. О.О. Галкіна НАН України
Физика и техника высоких давлений
Electrical properties of ZrO₂ in nano- and polycrystalline states at high pressure
Article
published earlier
spellingShingle Electrical properties of ZrO₂ in nano- and polycrystalline states at high pressure
Korionov, I.V.
Trefilova, A.N.
Babushkin, A.N.
Korionova, I.G.
Shumina, U.N.
Lojkowski, W.
Opalinska, A.
title Electrical properties of ZrO₂ in nano- and polycrystalline states at high pressure
title_full Electrical properties of ZrO₂ in nano- and polycrystalline states at high pressure
title_fullStr Electrical properties of ZrO₂ in nano- and polycrystalline states at high pressure
title_full_unstemmed Electrical properties of ZrO₂ in nano- and polycrystalline states at high pressure
title_short Electrical properties of ZrO₂ in nano- and polycrystalline states at high pressure
title_sort electrical properties of zro₂ in nano- and polycrystalline states at high pressure
url https://nasplib.isofts.kiev.ua/handle/123456789/70292
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