Структура молекулярного димерного алкоксокомплексу хрому (ІІІ) з диметил-N-трихлороацетиламідофосфатом
A new coordination compound of chromium (III) with dimethyl-N-trichloroacetylamidophosphate (L¯ = Cl3CC(O)NP(O)(OCH3)2) has been obtained. Based on IR data, the bidentate coordination mode of the carbacylamidophosphate ligand is suggested. The centrosymmetric bi-nuclear complex [Cr2(L)4(μ2−OCH3)2] h...
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| Date: | 2008 |
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| Main Authors: | , , , |
| Format: | Article |
| Language: | Ukrainian |
| Published: |
Видавничий дім "Академперіодика" НАН України
2008
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| Subjects: | |
| Online Access: | https://nasplib.isofts.kiev.ua/handle/123456789/7495 |
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| Journal Title: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Cite this: | Структура молекулярного димерного алкоксокомплексу хрому (ІІІ) з диметил-N-трихлороацетиламідофосфатом / Є.А. Труш, В.А. Труш, К.В. Домасевич, В.М. Амiрханов // Доп. НАН України. — 2008. — № 12. — С. 130-135. — Бібліогр.: 14 назв. — укр. |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine| Summary: | A new coordination compound of chromium (III) with dimethyl-N-trichloroacetylamidophosphate (L¯ = Cl3CC(O)NP(O)(OCH3)2) has been obtained. Based on IR data, the bidentate coordination mode of the carbacylamidophosphate ligand is suggested. The centrosymmetric bi-nuclear complex [Cr2(L)4(μ2−OCH3)2] has molecular structure according to X-ray analysis. The phosphoramidic ligands are coordinated in a bidentate manner via oxygen atoms of phosphoryl and carbonyl groups, and the coordination polyhedra represent the cis-isomer. The coordination environment of the central ion possesses a distorted octahedral geometry with c.n. = 6. The polyhedron (CrO6) comprises 4O from two bidentate phosphorylic ligands and 2O from bridging methoxide ions.
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| ISSN: | 1025-6415 |