Окиснення циклічних кетонів H2O2, каталізоване координаційними полімерами Cu(II) та Fe(III)

• Published in: Журнал органічної та фармацевтичної хімії
• Date: 2025
• Volume: 22
• Issue: 4
• Pages: 25-35
• ISSN: 2518-1548
• Author Affiliations: Emir N. Abdullayev — L.V. Pisarzhevsky Institute of Physical Chemistry of the National Academy of Sciences of Ukraine; Andrii M. Mishura — L.V. Pisarzhevsky Institute of Physical Chemistry of the National Academy of Sciences of Ukraine; Ievgenii A. Iermolenko — Enamine Ltd.; Institute of Organic Chemistry of the National Academy of Sciences of Ukraine; Anton S. Lytvynenko — L. V. Pisarzhevsky Institute of Physical Chemistry of the National Academy of Sciences of Ukraine; Maksim O. Kolosov — V. N. Karazin Kharkiv National University — ORCID: 0009-0009-3509-5752; Olena G. Shvets — V. N. Karazin Kharkiv National University; Kostyantyn S. Gavrilenko — Enamine Ltd.; Taras Shevchenko National University of Kyiv; Sergiy V. Kolotilov — L. V. Pisarzhevsky Institute of Physical Chemistry of the National Academy of Sciences of Ukraine
• Main Authors: Abdullayev, Emir N., Mishura, Andrii M., Iermolenko, Ievgenii A., Lytvynenko, Anton S., Kolosov, Maksim O., Shvets, Olena G., Gavrilenko, Kostyantyn S., Kolotilov, Sergiy V.
• Format: Article
• Language: English
• Published: National University of Pharmacy 2025
• Subjects: каталітичне окиснення; циклічні кетони; пероксид водню; пористі координаційні полімери; мідь(II); залізо(III)
• Online Access: https://ophcj.nuph.edu.ua/article/view/315358
• Journal Title: Journal of Organic and Pharmaceutical Chemistry

It has been shown that the oxidation of ketones – analogs of cyclohexanone – by hydrogen peroxide in the presence of Cu3(btc)2 (btc3- = 1,3,5-benzenetricarboxylate) occurred mainly by the radical mechanism, rather than by the Baeyer-Villiger reaction mechanism, and led to a mixture of products forme...