Regularities of epoxidized alkyl oleates ring-opening reactions with alcohols, water and organic acids in the presence of commercial sulfonated resins as catalysts

• Published in: Каталіз та нафтохімія
• Date: 2024
• Issue: 35
• Pages: 72-90
• ISSN: 2707-5796
• Author Affiliations: David Z. Davitadze — V.P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry of National Academy of Sciences of Ukraine 50 Kharkivske shausse, Kyiv, 02160, Ukraine; Sergiy V. Konovalov — V.P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry of National Academy of Sciences of Ukraine 1 Academician Kukhar Str., Kyiv, 02094, Ukraine
• Main Authors: Davitadze, David Z., Konovalov, Sergiy V.
• Format: Article
• Language: English
• Published: V.P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry of the National Academy of Sciences of Ukraine 2024
• Subjects: жирний епоксид; розкриття оксиранового циклу; сульфокатіоніти; твердий кислотний каталізатор; алкоксилювання; гідроліз; ацилювання; ізомеризація
• Online Access: https://kataliz.org.ua/index.php/journal/article/view/112
• Journal Title: Catalysis and petrochemistry

Current paper deals with the use of sulfonated resins, distinguished by the porous structure (macroreticular Purolite CT275 and gel-type CU-2-8ChS), as solid acid catalysts for syntheses of perspective components of biolubricants via oxirane ring-opening reactions of fatty epoxides with water (hydro...