Реакції дикетону Куксона з галогенідами калію в середовищі поліфосфорної кислоти

• Published in: Журнал органічної та фармацевтичної хімії
• Date: 2020
• Volume: 18
• Issue: 1(69)
• Pages: 34-38
• ISSN: 2518-1548
• Author Affiliations: Oleksandr V. Gaidai — National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”; Yevheniia Yu. Zhyhadlo — National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”; Igor A. Levandovskiy — National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”; Olena G. Sidorenko — National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”; Oleg V. Shishkin — State Scientific Institution “Institute for Single Crystals” of the National Academy of Sciences of Ukraine; Svitlana V. Shishkina — State Scientific Institution “Institute for Single Crystals” of the National Academy of Sciences of Ukraine; Yuliya V. Rassukana — Institute of Organic Chemistry of the National Academy of Sciences of Ukraine
• Main Authors: Gaidai, Oleksandr V., Zhyhadlo, Yevheniia Yu., Levandovskiy, Igor A., Sidorenko, Olena G., Shishkin, Oleg V., Shishkina, Svitlana V., Rassukana, Yuliya V.
• Format: Article
• Language: English
• Published: National University of Pharmacy 2020
• Subjects: дикетон Куксона; поліфосфорна кислота; розкриття циклу; CS-трисгомокубан; відновлення; УДК 547-316 54.057
• Online Access: https://ophcj.nuph.edu.ua/article/view/ophcj.20.186967
• Journal Title: Journal of Organic and Pharmaceutical Chemistry

Aim. To study the rearrangement of Cookson’s diketone by the action of potassium halides under conditions of polyphosphoric acid catalysis.Results and discussion. Chemical behaviour of Cookson’s diketone (CS-trishomocubane-8,11-dione) in the reactions with potassium halides (KCl, KBr, KI) in the pol...