Нековалентні взаємодії в просторово-утруднених олефінових катіон-радикалах

• Published in: Журнал органічної та фармацевтичної хімії
• Date: 2020
• Volume: 18
• Issue: 1(69)
• Pages: 05-13
• ISSN: 2518-1548
• Author Affiliations: Andrey A. Fokin — National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”; Vladislav V. Bahonsky — National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute” Justus-Liebig University Giessen, Institute of Organic Chemistry; Tetyana V. Koso — Justus-Liebig University Giessen, Institute of Organic Chemistry University of Helsinki, Materials Chemistry Division, Department of Chemistry, Faculty of Science — ORCID: 0000-0002-0429-3205; Ngo T. Hoc — National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute” Justus-Liebig University Giessen, Institute of Organic Chemistry; Michael Serafin — Justus-Liebig University Giessen, Institute of Inorganic and Analytical Chemistry; Tetyana S. Zhuk — National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute” — ORCID: 0000-0002-0046-8450; Volodymyr M. Rodionov — National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute” — ORCID: 0000-0002-7164-4458; Peter R. Schreiner — Institute of Organic Chemistry, Justus-Liebig University, Giessen, Germany
• Main Authors: Fokin, Andrey A., Bahonsky, Vladislav V., Koso, Tetyana V., Hoc, Ngo T., Serafin, Michael, Zhuk, Tetyana S., Rodionov, Volodymyr M., Schreiner, Peter R.
• Format: Article
• Language: English
• Published: National University of Pharmacy 2020
• Subjects: гіперкон’югація; потенціали іонізації; нековалентні взаємодії; олефіни; катіон-радикали; УДК 547.51 547.87
• Online Access: https://ophcj.nuph.edu.ua/article/view/ophcj.20.189679
• Journal Title: Journal of Organic and Pharmaceutical Chemistry

Aim. To study the effect of electronic (α- and β-hyperconjugations) and steric (noncovalent interactions) factors on the structures of olefinic radical cations.Results and discussion. The effect of intramolecular dispersion interactions on the structures of crowded alkenes in the neutral and ionized...