Новий зручний спосіб отримання тетрабутиламоній клозо-додекаборату

• Date: 2025
• Main Authors: Mishchenko, Artem M., Nechayev, Maxim A., Subota, Andrii I., Kozytskiy, Andriy V., Svaliavyn, Oleh V., Lishchenko, Yulian L., Aleksandrova, Anastasiia M., Rassukana, Yuliya V., Leha, Dmytro O.
• Format: Article
• Language: English
• Published: National University of Pharmacy 2025
• Subjects: клозо-додекаборат; октагідротриборат; піроліз; DFT-розрахунки
• Online Access: https://ophcj.nuph.edu.ua/article/view/316264
• Journal Title: Journal of Organic and Pharmaceutical Chemistry

A new synthetic procedure for preparing tetrabutylammonium closo-dodecaborate (Bu4N)2B12H12 by the solvent-free pyrolysis of tetrabutylammonium tetrahydroborate Bu4NBH4 has been developed. The procedure also provides isolation of pure tetrabutylammonium octahydrotriborate Bu4NB3H8 as a by-product. T...