Удосконалений синтез ROCKYPhos та його застосування для асиметричного гідрування похідних дигідроізохіноліну

An optimized approach to the multigram synthesis of [(1R,2R,3S)-(+)-1,2-dimethyl-2,3-bis(diphenylphosphinomethyl)cyclopentyl]methanol (ROCKYPhos, CatASium I®), a camphor-derived chiral diphosphine ligand, has been developed. The key improvement in the synthetic scheme involved the oxidative cleavage...

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Bibliographic Details
Date:2026
Main Authors: Bilenko, Vitalii A., Gorichko, Marian V.
Format: Article
Language:English
Published: National University of Pharmacy 2026
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Online Access:https://ophcj.nuph.edu.ua/article/view/353838
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Journal Title:Journal of Organic and Pharmaceutical Chemistry

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Journal of Organic and Pharmaceutical Chemistry