Протонна провідність та релаксаційні процеси в системі пірогенний алюмокремнезем – вода

The aim of the paper is investigation of relaxation processes and proton conductivity observed in water structures formed in 1–10 wt. % aqueous suspensions of fumed silica or alumina/silica. The latter contains 1–8 wt. % of alumina. The experiments have been performed using thermally stimulated depo...

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Збережено в:
Бібліографічні деталі
Дата:2012
Автори: Andriyko, L. S., Zarko, V. I., Goncharuk, E. V., Gun'ko, V. M.
Формат: Стаття
Мова:Українська
Опубліковано: Chuiko Institute of Surface Chemistry National Academy of Sciences of Ukraine 2012
Онлайн доступ:https://www.cpts.com.ua/index.php/cpts/article/view/172
Теги: Додати тег
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Назва журналу:Chemistry, Physics and Technology of Surface

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Chemistry, Physics and Technology of Surface
Опис
Резюме:The aim of the paper is investigation of relaxation processes and proton conductivity observed in water structures formed in 1–10 wt. % aqueous suspensions of fumed silica or alumina/silica. The latter contains 1–8 wt. % of alumina. The experiments have been performed using thermally stimulated depolarization current method. It has been shown that oxides promote the formation of 3D network with nanoparticles–water clusters causing the redistribution of sizes of water clusters observed in TSDC spectra. New relaxed structures are formed by nanosilica and these structures are unavailable in the bulk water.