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Бекманівське перегрупування циклогексанонооксиму в ?-капролактам на сульфосмолі Dowex DR-2030 у присутності диметилсульфоксиду

It has been shown that Dowex DR-2030 provides 100% conversion of cyclohexanone oxime (17 wt.% solution in DMSO) with 80–85% ?-caprolactam yield at 100–120°C (LHSV = 1 h-1). By the results on quantumchemical simulation of Beckmann rearrangement of cyclohexanone oxime, DMSO promotes lowering of energy...

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Bibliographic Details
Date:2013
Main Authors: Brei, V. V., Bodyul, N. S., Grebenyuk, A. G.
Format: Article
Language:Russian
Published: Chuiko Institute of Surface Chemistry National Academy of Sciences of Ukraine 2013
Online Access:https://www.cpts.com.ua/index.php/cpts/article/view/202
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Journal Title:Chemistry, Physics and Technology of Surface

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Chemistry, Physics and Technology of Surface

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