Counting the effect of support polarization charge on the spectra of orientation-ordered adsorbate monolayers
This article takes a due regard of influence caused by polarization charge of the substrate on the spectroscopic characteristics of the orientationally ordered adsorbed monolayers. The expression for the power of IR radiation, absorbed by polarization charge of the substrate, was inferred. &...
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| Date: | 2007 |
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| Main Authors: | , |
| Format: | Article |
| Language: | Russian |
| Published: |
Chuiko Institute of Surface Chemistry National Academy of Sciences of Ukraine
2007
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| Online Access: | https://surfacezbir.com.ua/index.php/surface/article/view/205 |
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| Journal Title: | Surface |
| Download file: |  |
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Surface| Summary: | This article takes a due regard of influence caused by polarization charge of the substrate on the spectroscopic characteristics of the orientationally ordered adsorbed monolayers. The expression for the power of IR radiation, absorbed by polarization charge of the substrate, was inferred.  As a result the factor was obtained to be included in the known formulae for integral intensities of spectral lines. In the papers, we know, the alike consideration was not quite consequent, which hindered the adequate regard of this influence. The main aim of the current paper is to fill in this gap. |
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