Comparative mass-spectrometric study on the interaction of linear and branched homologs of valerianic and pivalinic acids with silica surface

Interaction of linear and branched molecules of valeric and pivalic acids with the surface of fumed silica has been studied by the temperature-programmed desorption mass spectrometry. Structure of adsorption complex, mechanisms of chemisorptions and destruction of chemisorpted acids have been propos...

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Datum:2007
Hauptverfasser: Kulik, T. V., Palyanitsa, B. B., Azizova, L. R., Таrnavskiy, S. S.
Format: Artikel
Sprache:Russisch
Veröffentlicht: Chuiko Institute of Surface Chemistry National Academy of Sciences of Ukraine 2007
Online Zugang:https://surfacezbir.com.ua/index.php/surface/article/view/210
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Назва журналу:Surface
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Surface
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Zusammenfassung:Interaction of linear and branched molecules of valeric and pivalic acids with the surface of fumed silica has been studied by the temperature-programmed desorption mass spectrometry. Structure of adsorption complex, mechanisms of chemisorptions and destruction of chemisorpted acids have been proposed. Kinetic parameters of chemical transformation of investigated acid on the surface of fumed silica had been calculated.