Fire extinguishing capability of phosphorus-containing silica

Samles of fire extinguishing powders have been obtained due to following the results of quantum chemical calculations on reactivity of phosphorus-containing compounds and radicals (both gas phase and grafted to silica surface). Their activity has been checked in extinguishing oxygen-hydrogen flame....

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Збережено в:
Бібліографічні деталі
Дата:2007
Автори: Kukueva, V. V., Lobanov, V. V., Bogatyrev, V. M., Grebenyuk, A. G., Tropinov, O. G.
Формат: Стаття
Мова:Російська
Опубліковано: Chuiko Institute of Surface Chemistry National Academy of Sciences of Ukraine 2007
Онлайн доступ:https://surfacezbir.com.ua/index.php/surface/article/view/225
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Назва журналу:Surface
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Резюме:Samles of fire extinguishing powders have been obtained due to following the results of quantum chemical calculations on reactivity of phosphorus-containing compounds and radicals (both gas phase and grafted to silica surface). Their activity has been checked in extinguishing oxygen-hydrogen flame. The greater extinguishing activity of phosphorus-containing samples as compared with that of the standard P2-APM powder has been shown to be connected with both dicrease in bond dissociation energy for surface compounds on modified silica and ultradisperse state of phosphorus-containing silica.