Конверсія суміші пропіленгліколь-ацетон в 2,2,4-триметіл-1,3-діоксолан на кислотних Dowex DR-2030 и ZrO2-SiO2 каталізаторах

The conversion of propylene glycol-acetone mixtures into cyclic ketal over sulforesin Dowex DR-2030 and acidic ZrO2-SiO2 catalysts under steady conditions at 40–100°C has been studied. It has been shown that 2,2,4-trymethyl-1,3-dioxolane can be obtained with 99–94°% yield at 40–50°C. Conversion of p...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Datum:2014
Hauptverfasser: Sontsev, V. M., Brei, V. V.
Format: Artikel
Sprache:Russian
Veröffentlicht: Chuiko Institute of Surface Chemistry National Academy of Sciences of Ukraine 2014
Schlagworte:
Online Zugang:https://www.cpts.com.ua/index.php/cpts/article/view/260
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Назва журналу:Chemistry, Physics and Technology of Surface

Institution

Chemistry, Physics and Technology of Surface
Beschreibung
Zusammenfassung:The conversion of propylene glycol-acetone mixtures into cyclic ketal over sulforesin Dowex DR-2030 and acidic ZrO2-SiO2 catalysts under steady conditions at 40–100°C has been studied. It has been shown that 2,2,4-trymethyl-1,3-dioxolane can be obtained with 99–94°% yield at 40–50°C. Conversion of propylene glycol increases from 65 to 75% when providing of the ketalization process with water removing.