Адсорбція аліфатичних карбонових кислот на поверхні кремнезему

A study has been carried out of interaction of the lowest members of homologous series of aliphatic carboxylic acids with the high-dispersed silica surface by IR-spectroscopy, quantum chemical and adsorptive methods. Values of Gibbs free energies and of constants of adsorption equilibrium have been...

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Bibliographic Details
Date:2008
Main Authors: Azizova, L. R., Palyanitsa, B. B., Kazakova, O. O., Kulik, T. V.
Format: Article
Language:Ukrainian
Published: Chuiko Institute of Surface Chemistry National Academy of Sciences of Ukraine 2008
Online Access:https://surfacezbir.com.ua/index.php/surface/article/view/269
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Journal Title:Surface
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Summary:A study has been carried out of interaction of the lowest members of homologous series of aliphatic carboxylic acids with the high-dispersed silica surface by IR-spectroscopy, quantum chemical and adsorptive methods. Values of Gibbs free energies and of constants of adsorption equilibrium have been obtained. No regular change has been found of -DGads value depending on the number of methylene groups in acid molecule.