Influence of surface structure of silica adsorbents on their conducting properties

In the present work conductivity-concentration relationships have been studied by conductometric method of systems macroporous silica adsorbent – solution of 1,1 charge electrolyte as dependent on hydrochloric acid concentration. The content of counter- and co-ions in solid phase was estimated. It w...

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Datum:2008
Hauptverfasser: Dzyaz'ko, Yu. S., Belyakova, L. A.
Format: Artikel
Sprache:Russisch
Veröffentlicht: Chuiko Institute of Surface Chemistry National Academy of Sciences of Ukraine 2008
Online Zugang:https://surfacezbir.com.ua/index.php/surface/article/view/275
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Назва журналу:Surface
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Zusammenfassung:In the present work conductivity-concentration relationships have been studied by conductometric method of systems macroporous silica adsorbent – solution of 1,1 charge electrolyte as dependent on hydrochloric acid concentration. The content of counter- and co-ions in solid phase was estimated. It was shown that co-ionic mobility can exceed counterionic one at overlapping of duffusion layers in intra-cell solution. A dependence of electric conductivity of functional silica materials on chemical composition and their surface structure was demonstrated. The cause of change in electric conductivity for β-cyclodextrin-containing silicas was found.