Αcid-base properties of 3 aminopropyl-containing xerogels

Acid-base properties of amine group-containing xerogels synthesized by sol-gel tech­nique have been studied by pH-metric titration. Protonation (lgKprot) and conjugation (lgKcon) constants of surface 3-aminopropyl groups were calculated using electrostatic model and that of chemical reaction. An inc...

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Збережено в:
Бібліографічні деталі
Дата:2008
Автори: Goncharyk, V. P., Kozhara, L. I., Zub, Yu. L.
Формат: Стаття
Мова:Російська
Опубліковано: Chuiko Institute of Surface Chemistry National Academy of Sciences of Ukraine 2008
Онлайн доступ:https://surfacezbir.com.ua/index.php/surface/article/view/277
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Назва журналу:Surface
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Резюме:Acid-base properties of amine group-containing xerogels synthesized by sol-gel tech­nique have been studied by pH-metric titration. Protonation (lgKprot) and conjugation (lgKcon) constants of surface 3-aminopropyl groups were calculated using electrostatic model and that of chemical reaction. An increase has been found in lgKprot with surface amino group con­centration in xerogels whereas no dependence of lgKcon on their concentration has been revealed.